Manganese(Ⅱ)and Copper(Ⅰ)Compounds Based on Two Derivatives of Imidazo[1,5-a]pyridine:Synthesis,Structures,Magnetic Properties,and Catalytic Activity  

作　　者：ZHANG Qian CUI Yan-Feng ZHANG Xia-Mei LI Ya-Hong YAO Jin-Lei 张茜;崔燕峰;张夏梅;李亚红;姚金雷(College of Chemistry,Chemical Engineering and Materials Science,Soochow University,Suzhou 215123,China;Jiangsu Key Laboratory of Micro and Nano Heat Fluid Flow Technology and Energy Application,School of Physical Science and Technology,Suzhou University of Science and Technology,Suzhou 215009,China)

机构地区：[1]College of Chemistry,Chemical Engineering and Materials Science,Soochow University,Suzhou 215123,China [2]Jiangsu Key Laboratory of Micro and Nano Heat Fluid Flow Technology and Energy Application,School of Physical Science and Technology,Suzhou University of Science and Technology,Suzhou 215009,China

出　　处：《Chinese Journal of Structural Chemistry》2022年第3期148-154,I0011,共8页结构化学（英文）

基　　金：supported by the National Natural Science Foundation of China (21772140, 21771136);Natural Science Foundation of Jiangsu Province (BK20171213);the Priority Academic Program Development of Jiangsu Higher Education Institution;the Project of Scientific and Technologic Infrastructure of Suzhou (SZS201905)

摘　　要：The utilization of 2,6-bis(imidazo[1,5-a]pyridin-3-yl)pyridine(bipp)and 3-(pyridin-2-yl)imidazo[1,5-a]pyridine(pip)in the compounds of manganese(Ⅱ)and copper(Ⅰ)ions is presented.Two complexes,[Mn(bipp)(SO_(4))(H_(2)O)]n(1)and[Cu(pip)_(2)]ClO_(4)(2),were prepared with different characteristics in structure.Compound 1 exhibits a one-dimensional chain topology,and 2 is a homoleptic Cu(Ⅰ)complex.The dc magnetic susceptibility investigations reveal the antiferromagnetic(AF)MnⅡ···MnⅡinteractions in complex 1.The catalytic activity of compound 2 toward ketalization reactions was studied.Complex 2 exhibits high activity for the ketalization transformations of aliphatic ketones.

关 键 词：coordination complexes chain configuration MAGNETISM CATALYSIS 

分 类 号：O641.4[理学—物理化学]