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作 者:WANG Yi-Feng SHU Mou-Hai 王逸风;舒谋海(School of Chemistry and Chemical Engineering,Frontiers Science Center for Transformative Molecules,Shanghai Jiao Tong University,Shanghai 200240,China)
出 处:《Chinese Journal of Structural Chemistry》2022年第3期186-192,I0012,共8页结构化学(英文)
基 金:Financial support from the Natural Science Foundation of Shanghai (No. 19ZR1424900)
摘 要:The preparation method of a funnel like ligand derived from calix[6]arene and tris(2-pyridyl-methyl)anime has been improved.The Cu(Ⅱ)complex was obtained and characterized by ESI-MS,EPR,UV-Vis spectra and crystallographic analysis.In the complex,a guest acetonitrile molecule is introduced into the cavity of the ligand host via the coordination with Cu(Ⅱ)center.
关 键 词:Cu(Ⅱ)complex crystal structure calix(6)arene host-guest interaction
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