Synthesis,Structure and Properties of an Iron Complex with Formally Zero Oxidation State  

作　　者：ZHU Lin-Jun HUANG Tao ZHANG Teng 朱林君;黄桃;张腾(State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China;University of the Chinese Academy of Sciences,Beijing 100049,China)

机构地区：[1]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China [2]University of the Chinese Academy of Sciences,Beijing 100049,China

出　　处：《Chinese Journal of Structural Chemistry》2022年第3期235-240,I0013,共7页结构化学（英文）

基　　金：supported by Talent Recruitment Program of Fujian Province

摘　　要：An unusual iron complex with formally zero oxidation state,iron bis(6,6'-dimethyl-2,2'-bipyridine),was synthesized and its crystal structure was determined.Combination of experimental and theoretical studies reveals that the electronic structure of the complex is best described as Fe(Ⅱ)(Mebipy-)2 with anionic Mebipyligands and high-spin Fe(Ⅱ)center.

关 键 词：Fe(Mebipy)2 crystal structure electronic structure redox-active ligand 

分 类 号：O641.4[理学—物理化学]