黑磷烯纳米阻燃剂研究进展  

Research progress in development and applications of black phosphorene for flame retardancy of polymers

作　　者：孙旗 高兴 崔雪梅 连慧琴[1] 崔秀国[1] 汪晓东[2] SUN Qi;GAO Xing;CUI Xuemei;LIAN Huiqin;CUI Xiuguo;WANG Xiaodong(Beijing Key Lab of Special Elastomeric Composite Materials,School of New Materials and Chemical Engineering,Beijing Institute of Petrochemical Technology,Beijing 102617,China;State Key Laboratory of Organic-Inorganic Composites,Beijing University of Chemical Technology,Beijing 100029,China;Shandong Yueneng New Materials Science&Technology Co,Ltd,Shouguang 262713,China)

机构地区：[1]北京石油化工学院新材料与化工学院,特种弹性体及复合材料北京市重点实验室,北京102617 [2]北京化工大学有机无机复合材料国家重点实验室,北京100029 [3]山东玥能新材料科技有限公司,山东寿光262713

出　　处：《中国塑料》2022年第5期133-139,共7页China Plastics

基　　金：国家自然科学基金(51573021)。

摘　　要：黑磷烯是一种具有独特性能的新型二维纳米材料,所具备的窄带半导体性能特征,使其在场效应晶体管、光电子器件、自旋电子学、气体传感器及太阳能电池等方面具有广阔的应用前景。近年来,黑磷烯用于聚合物阻燃已成为新的热点研究领域。本文阐述了黑磷烯的制备技术及阻燃机理,详细介绍了黑磷烯作为阻燃剂用于环氧树脂(EP)、聚氨酯(PU)和聚丙烯腈等聚合物阻燃的研究进展,分析了黑磷烯阻燃剂在应用中存在的问题,并对黑磷烯阻燃剂未来的发展方向进行了展望。Black phosphorene is a new type of two-dimensional nanomaterial with unique properties,and its narrow-band semiconductor properties make it a broad application prospect in field-effect transistors,optoelectronic devices,spintroni cs,gas sensors,and solar cells.In recent years,the use of black phosphorene for the flame retardancy of polymers has become a hot research field.This paper reviewed the latest research progress in the preparation technology and flame re-tardant mechanism of black phosphorene.The research advances in the use of black phosphorene as a flame retardant for polymers such as epoxy resin,polyurethane and polyacrylonitrile were introduced.Then,the problems in the flame-retar-dant application of black phosphorus were analyzed,and the future development direction of the black phosphorene-based flame retardants was prospected.

关 键 词：黑磷烯 二维纳米材料 阻燃 聚合物 研究进展 

分 类 号：TQ314.248[化学工程—高聚物工业]