C(sp^(3))-H bond functionalization of oximes derivatives via 1,5-hydrogen atom transfer induced by iminyl radical  

作　　者：Dao-Qing Dong Jing-Cheng Song Shao-Hui Yang Qi-Xue Qin Zu-Li Wang En-Xuan Zhang Yuan-Yuan Sun Qing-Qing Han Shan Yue 

机构地区：[1]College of Chemistry and Pharmaceutical Sciences,Qingdao Agricultural University,Qingdao 266109,China [2]Asymchem Life Science(Tianjin)Co.,Ltd.,Tianjin 300457,China

出　　处：《Chinese Chemical Letters》2022年第3期1199-1206,共8页中国化学快报（英文版）

基　　金：supported by the National Natural Science Foundation of China (Nos. 21772107, 21901010);Shandong Province Key Research and Development Plan (No. 2019GSF108017)。

摘　　要：Oximes derivatives have been vastly used in organic synthesis. In this review, C(sp^(3))-H bond functionalization of oximes derivatives via iminyl radical induced 1,5-hydrogen atom transfer was discussed. According to the different type of products, this review was divided into three parts: (1) C(sp^(3))-H bond functionalization for C-C bond formation. (2) C(sp^(3))-H bond functionalization for C-N bond formation. (3) C(sp^(3))-H bond functionalization for C-S, C-F bond formation.

关 键 词：Oximes derivatives 1 5-hydrogen atom transfer Iminyl radicals C(sp^(3))-H Bond Visible light 

分 类 号：O621.25[理学—有机化学]