磷酸盐玻璃结构与性能的研究进展  

Research Progresses on Structures and Properties of Phosphate Glasses

作　　者：严静萍 邓路 胡丽丽[1] YAN Jingping;DENG Lu;HU Lili(Shanghai Institute of Optics and Fine Mechanics,Chinese Academy of Sciences,Shanghai 201800,China;University of Chinese Academy of Sciences,Beijing 100049,China)

机构地区：[1]中国科学院上海光学精密机械研究所,上海201800 [2]中国科学院大学,北京100049

出　　处：《硅酸盐学报》2022年第4期1006-1021,共16页Journal of The Chinese Ceramic Society

基　　金：国防科工局资助项目(FKY1683 ZHG001SSJS-B01-001)。

摘　　要：磷酸盐系统玻璃由于其独特的析晶性、耐化学腐蚀性、以及光学、力学、热学、电学等方面的性能,在包括密封材料、光学元器件、生物医学玻璃、固体电解质、核废物贮存等方面有着广泛的应用。本综述结合了实验表征和材料计算模拟两方面的研究,整理了磷酸盐玻璃的结构、物理化学性能、以及两者间关系的研究现状,总结了实验表征和材料计算手段在相关研究上的应用及其相互间的对比验证,并进一步对磷酸盐玻璃研究的未来发展进行了展望。Phosphate glasses are widely used in various applications like sealing materials,optical components,biomedical glass,solid electrolytes,and nuclear waste disposal due to their unique crystallization behavior,chemical durability,as well as the optical,mechanical,thermal,and electrical properties.This review summarized recent research progress on the structure features,the physical and chemical properties as well as the relationship between the structure and properties of these particular systems based on the experimental observations and computational simulation results.The results from the experiment and simulation were compared.In addition,the future possibilities for the development and application of phosphate glasses were also given.

关 键 词：磷酸盐玻璃 结构与性质 分子动力学模拟 析晶性 耐化学腐蚀性 

分 类 号：J527.3[艺术—艺术设计]