气相色谱串联质谱分析引起蜜蜂中毒的农药及其代谢物  

Analysis of pesticides and their metabolites causing bee poisoning by gas chromatography tandem mass spectrometry

作　　者：周萍 李珊珊 尹志红 吴晓群 李樱红 胡福良[2] Zhou Ping;Li Shanshan;Yin Zhihong;Wu Xiaoqun;Li Yinghong;Hu Fuliang(Hangzhou Biyutian Health Products Co.Ltd.,Tonglu 311500;Animal Science College of Zhejiang University,Hangzhou 310058;Tonglu County Market Supervision and Administration Bureau,Tonglu 311500;Zhejiang Institute forFood and Drug Control,Hangzhou 310052)

机构地区：[1]杭州碧于天保健品有限公司,桐庐311500 [2]浙江大学动物科学学院,杭州310058 [3]桐庐县市场监管局,桐庐311500 [4]浙江省食品药品检验研究院,杭州310052

出　　处：《中国蜂业》2022年第5期54-57,共4页Apiculture of China

基　　金：财政部和农业农村部:国家现代农业产业技术体系建设项目(CARS-44);2021年度浙江省市场监督管理局科技项目(20210127)。

摘　　要：运用气相色谱串联质谱法测定健康蜜蜂、中毒蜜蜂和可疑蜂药。结果表明:中毒蜜蜂中含有禁用的克螨特、蝇毒磷及双甲脒代谢物,最高浓度达到7920μg/kg。可疑蜂药中检出禁用蜂药成分克螨特、蝇毒磷,最高浓度达到9250 mg/kg。分析了蜜蜂中毒可能的原因,提出了科学使用蜂药的建议。Gas chromatography tandem mass spectrometry was used to determine healthy and poisoned bees as well as suspected bee drugs.The results showed that the poisoned bees contained banned metabolites of chlorimid,fly toxic phosphorus and amitraz,and the highest concentration was 7920μg/kg.The banned bee medicine components of ketamite and fl y toxic phosphorus were detected in the suspected bee medicine,and the maximum concentration was 9250 mg/kg.The causes of bee poisoning were analyzed,and the suggestions on the scientifi c use of bee medicine were put forward.

关 键 词：气相色谱串联质谱 蜜蜂中毒 农药 原因分析 

分 类 号：S895.9[农业科学—特种经济动物饲养]