废旧棉与涤纶纺织品化学法循环再生利用的研究进展  

Research progress in chemical recycling of waste cotton and polyester textiles

作　　者：陈龙[1] 周哲[1] 张军[2] 徐世美 倪延朋 CHEN Long;ZHOU Zhe;ZHANG Jun;XU Shimei;NI Yanpeng(College of Material Science and Engineering, Donghua University, Shanghai 201620, China;Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;College of Chemistry, Sichuan University, Chengdu, Sichuan 610064, China;College of Textiles and Clothing, Qingdao University, Qingdao, Shandong 206071, China)

机构地区：[1]东华大学材料科学与工程学院,上海201620 [2]中国科学院化学研究所,北京100190 [3]四川大学化学学院,四川成都610207 [4]青岛大学纺织服装学院,山东青岛266071

出　　处：《纺织学报》2022年第5期43-48,共6页Journal of Textile Research

基　　金：国家重点研发计划项目(2020YFC1910300)。

摘　　要：针对我国废旧纺织品中棉和涤纶制品产量高、循环利用率低、高品质产品少等问题,介绍了化学法循环再生利用废旧棉、涤纶纺织品的方法,分析了废旧棉再生浆粕及其纤维制备技术和废旧涤纶纺织品解聚单体及其再聚合技术的现状。相关研究表明:目前已能采用低比例废旧棉再生浆粕与原生木浆混合的方式实现废旧棉再生Lyocell纤维的小规模生产;采用乙二醇醇解-甲醇酯交换技术可实现废旧涤纶纺织品化学法再生聚酯的万吨级规模生产,但仍存在技术难度大、生产成本高、回收利用率低、产品品质差,且面临“治废产废”程度有待进一步降低等难题;开发废旧棉、涤纶纺织品清洁再生与高值化利用技术是废旧纺织品循环利用的发展趋势。A large number of waste cotton and polyester textiles are produced in China,but the recycling rate is low and high quality products are rare.Focusing on this problem,the recycling of waste cotton and polyester fabrics based on chemical recycling was reviewed.The technology of waste cotton pulp preparation and its fiber spinning,the monomer preparation from the depolymerization of waste polyester and its polymerization were examined.The literature review indicated that the small-scale production of waste cotton was involved in the making of regenerated Lyocell fibers by mixing low proportion of waste cotton regenerated pulp with the primary wood pulp,and that 10000-ton scale production of chemically regenerated polyethylene terephthalate(PET)from waste PET textiles has been achieved through glycol alcoholysis-methanol ester exchange technology.However,there are still problems such as technical difficulties,high production cost,low recovery and utilization rate,poor product quality,and high degree of"waste production caused by waste treatment".Hence,key technology development for waste textile recycling should be the focus of research emphasizing on clean recycling and high value utilization of waste cotton and polyester textiles.

关 键 词：纺织品 废旧棉 废旧涤纶 化学再生 循环再生 

分 类 号：TS106[轻工技术与工程—纺织工程]