芳基硅烷合成研究进展  

Research Progress in Synthesis of Arylsilane

作　　者：严妍 彭家建[1] 白赢[1] 厉嘉云[1] 余泽浩 刘俊 宋姿洁 刘鹏 YAN Yan;PENG Jiajian;BAI Ying;LI Jiayun;YU Zehao;LIU Jun;SONG Zijie;LIU Peng(Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education,College of Material,Chemistry and Chemical Engineering,Hangzhou Normal University,Hangzhou 311121,China)

机构地区：[1]杭州师范大学材料与化学化工学院有机硅化学及材料技术教育部重点实验室,浙江杭州311121

出　　处：《杭州师范大学学报（自然科学版）》2022年第3期225-237,275,共14页Journal of Hangzhou Normal University(Natural Science Edition)

基　　金：浙江省自然科学基金项目(LY18B020012).

摘　　要：芳基硅烷广泛应用于Hiyama偶联、C-N偶联、联芳烃及聚酮高分子化合物合成等方面,其合成研究受到关注.文章对近二十年来芳基硅烷的合成研究进行概述,发现利用贵金属催化剂催化芳基硅烷合成,虽然产物收率高、底物适用性好、反应时间短、反应条件温和,但也存在着催化剂成本高、难以回收利用的问题.非贵金属催化剂的开发研究以及催化剂循环利用将是今后重点关注的方向.Arylsilanes have been widely used in Hiyama coupling,C-N coupling,synthesis of biaryl and polyketone polymer compounds,and its research has received extensive attentions.In this paper,the synthetic research of arylsilane in the past two decades has been reviewed.It is found that the synthesis of arylsilane catalyzed by noble metal catalyst has the advantages of high product yield,good substrate applicability,short reaction time and mild reaction conditions.However,it also has the shortcomings of high catalyst cost and difficult recycling.Therefore,the development,research and recycling of non-noble metal catalysts will be the research focus in the future.

关 键 词：芳基硅烷合成 贵金属催化剂 非贵金属催化剂 

分 类 号：TQ426.6[化学工程]