三苯二噁嗪功能性染料的合成及应用研究进展  

Synthesis and application progress of triphenodioxazine functional dyes

作　　者：崔金海 张予东[2] 石海洋[3] 胡新成 CUI Jinhai;ZHANG Yudong;SHI Haiyang;HU Xincheng(College of Chemistry and Chemical Engineering,Shangqiu Normal University,Shangqiu 476000,Henan,China;College of Chemistry and Chemical Engineering,Henan University,Kaifeng 475004,Henan,China;School of Material and Chemical Engineering Kaifeng University,Kaifeng 475004,Henan,China)

机构地区：[1]商丘师范学院化学化工学院,河南商丘476000 [2]河南大学化学化工学院,河南开封475004 [3]开封大学材料与化工学院,河南开封475004

出　　处：《化学研究》2022年第3期272-282,共11页Chemical Research

基　　金：国家自然科学基金(U1904195)。

摘　　要：归纳了对称结构、非对称结构三苯二噁嗪化合物及三苯二噁嗪聚合物作为太阳能电池敏化染料、n-型有机半导体材料、二向色染料、超级电容器材料的应用及合成特点,探讨了三苯二噁嗪化合物的两种成环机理,并展望了三苯二噁嗪功能性染料的未来发展方向。Applications and synthesis on symmetric and asymmetric triphenodioxazine compounds and triphenodioxazine polymers in the field of sensitized dyes for solar cells,n-type organic semiconductor materials,dichroic dyes and supercapacitor materials were summarized.Two cyclization models of triphenodioxazine compounds were discussed as well.Furthermore,the development trends of triphenodioxazine functional dyes were prospected.

关 键 词：三苯二噁嗪 功能染料 应用 氧化闭环机理 

分 类 号：TQ9[化学工程]