化学工程与工艺专业开放实验:Pd/CeO_(2)催化生物质甘油氧化羰基化合成碳酸甘油酯  

Open Experiment for Students Majoring in Chemical Engineering and Technology:Oxidative Carbonylation of Glycerol to Glycerol Carbonate over Pd/CeO_(2)

作　　者：王志苗[1,2] 安华良 郭硕[1] 李芳 薛伟 Wang Zhimiao;An Hualiang;Guo Shuo;Li Fang;Xue Wei(Hebei Provincial Key Laboratory of Green Chemical Technology and High Effi cient Energy Saving,School of Chemical Engineering and Technology,Hebei University of Technology,Tianjin,300130;Tianjin Key Laboratory of Chemical Process Safety,Tianjin,300130)

机构地区：[1]河北工业大学化工学院,河北省绿色化工与高效节能重点实验室,天津300130 [2]天津市本质安全化工技术重点实验室,天津300130

出　　处：《当代化工研究》2022年第10期125-127,共3页Modern Chemical Research

基　　金：国家自然科学基金项目“负载功能化离子液体催化剂的制备及其在苯酚氧化羰基化反应中的应用”(项目编号:21776057)。

摘　　要：采用水热合成法制备了CeO_(2)纳米管(CeO_(2)-NT);并以其作为载体,利用浸渍法制备了负载型Pd催化剂Pd/CeO_(2)-NT,用于催化甘油氧化羰基化合成碳酸甘油酯(GC)。在优化的反应条件下,甘油转化率为93.5%,GC选择性达99.9%。这个实验是化学工程与工艺专业本科教学的一个开放性综合实验,要求学生能够独立查阅文献、在老师的指导下设计合理的实验方案、熟悉操作步骤和撰写报告,培养学生们的科研能力和创新意识,对以后开展科研工作大有裨益。CeO_(2)nanotubes were prepared by hydrothermal method,CeO_(2)-supported Pd catalyst(Pd/CeO_(2)-NT)was prepared using two-step hydrothermal impregnation and used in the oxidative carbonylation of glycerol to produce glycerol carbonate.Under optimized reaction conditions,the glycerol conversion was 93.5%,glycerol carbonate selectivity was 98.5%.The opening comprehensive experiment was designed for chemical engineering and technology of undergraduate teaching.The students need to literature searching,designing experimental scheme,operation and report writing independently.These contents were help to cultivate student,scientific research ability and innovative consciousness,as well as to carry out scientific research in the future.

关 键 词：本科教学 开放实验 碳酸甘油酯 甘油 氧化羰基化 

分 类 号：G642[文化科学—高等教育学]