电化学条件下苄醇到芳香醛的选择性氧化  

Chemselective Oxidation of Benzyl Alcohol to Aromatic Aldehyde under Electrochemical Conditions

作　　者：张金凤 蒋越 段荣琛 苏玉洁 孟令国[1] ZHANG Jinfeng;JIANG Yue;DUAN Rongchen;SU Yujie;MENG Lingguo(School of Chemistry,Huaibei Normal University,235000,Huaibei,Anhui,China)

机构地区：[1]淮北师范大学化学与材料科学学院,安徽淮北235000

出　　处：《淮北师范大学学报（自然科学版）》2022年第2期92-96,共5页Journal of Huaibei Normal University：Natural Sciences

基　　金：安徽高校自然科学研究项目(KJ2020B01);安徽省质量工程项目(2019rcsfjd046);淮北师范大学质量工程项目(2020xjxyj017)。

摘　　要：在电化学环境下,以四丁基醋酸铵为电解质,苄醇作为反应底物,在无金属、无催化剂参与的条件下,实现苄醇到醛的选择性氧化,与传统氧化合成相比,反应条件温和,操作简单.同时本实验的设计,可帮助化学类专业学生解电化学合成方法的基本原理,并在可持续发展战略的背景下传输绿色有机合成理念.This electrochemical innovative experiment employed tetrabutylammonium acetate as the electrolyte and benzyl alcohol as the reaction substrate,and realized the selective oxidation of benzyl alcohol to aldehyde without the participation of metal and catalyst.At the same time,this proposed innovative design experiment will help chemistry undergraduates learn the fundamentals of electrochemical synthetic methods,and implant green organic synthesis concept for students under the context of sustainable development strategies.

关 键 词：电催化 绿色合成 化学选择性氧化 苄醇 芳香醛 

分 类 号：O621.3[理学—有机化学]