三苯乙烯基苯酚嵌段聚醚硫酸酯铵盐的合成  

Synthesis of Tristyryl Phenol Block Polyether Ammonium Sulfate Ammonium Salt

作　　者：秦飞 赵炯烽 金一丰 Qin Fei;Zhao Jiongfeng;Jin Yifeng(Zhejiang Huangma New Material Co.,Ltd.,Shaoxing 312300;Zhejiang Huangma Technology Co.,Ltd.,Shaoxing 312300,China)

机构地区：[1]浙江皇马尚宜新材料有限公司,浙江绍兴312300 [2]浙江皇马科技股份有限公司,浙江绍兴312300

出　　处：《广东化工》2022年第9期1-4,共4页Guangdong Chemical Industry

摘　　要：三苯乙烯基苯酚聚氧乙烯聚氧丙烯醚与氨基磺酸在催化剂尿素催化作用下反应生成三苯乙烯基苯酚聚氧乙烯聚氧丙烯醚硫酸酯铵盐。考察反应气氛、原料投料比、反应时间、反应温度和催化剂用量对硫酸酯铵盐性能的影响。通过反应条件优化,确定最佳合成工艺条件:在氮气氛围下,氨基磺酸与聚醚摩尔比为0.9∶1,催化剂量为总投料量的1.5 wt%,反应温度120℃,反应时间2 h,产品中活性物含量超过87 wt%。Tristyryl phenol polyoxyethylene polyoxypropylene ether reacted with aminosulfonic acid under the catalysis of urea to produce tristyl phenol polyoxyethylene polyoxypropylene ether sulfate ammonium salt.The effects of reaction atmosphere,feed ratio,reaction time,reaction temperature and catalyst dosage on the properties of ammonium sulfate were investigated.Through the optimization of reaction conditions,the optimum synthesis conditions were determined:in nitrogen atmosphere,the molar ratio of aminosulfonic acid to polyether is 0.9∶1,the amount of catalyst is 1.5 wt%of the total feed,the reaction temperature is 120℃,the reaction time is 2 h,and the content of active substance in the product exceeds 87 wt%.

关 键 词：氨基磺酸 尿素 硫酸酯化 表面活性剂 正交试验 

分 类 号：TQ[化学工程]