活化H_(2)O_(2)的芬顿/类芬顿体系的研究现状  

Research status of Fenton/Fenton-like system for activating H_(2)O_(2)

作　　者：俞乙平 林少华[1] 钱子姣 YU Yi-ping;LIN Shao-hua;QIAN Zi-jiao(School of Civil Engineering,Nanjing Forestry University,Nanjing 210037,China)

机构地区：[1]南京林业大学土木工程学院,江苏南京210037

出　　处：《应用化工》2022年第4期1101-1108,1115,共9页Applied Chemical Industry

基　　金：国家重点研发计划课题(2017YFC0505803)。

摘　　要：论述了铁基催化剂芬顿技术的研究进展及不足;重点介绍了非铁基芬顿催化剂(如铈、铬、钴、铜、锰、钌、多金属氧盐酸和金纳米材料等)在应用时的氧化还原特征、优势和潜在应用领域;总结分析了非铁基催化剂在实际应用时的不足,并指出未来应继续寻求高效稳定的催化剂、发展非铁基强化类芬顿技术和探寻非铁基芬顿/类芬顿技术和其他工艺的组合/耦合技术。The research progress and shortcomings of Fenton technology of iron-based catalyst were discussed.The redox characteristics,advantages and potential application fields of non-iron-based Fenton catalysts(such as cerium,chromium,cobalt,copper,manganese,ruthenium,polymetallic oxyhydrochloric acid and gold nanomaterials,etc.)are emphatically introduced.The shortcomings of non-iron based catalysts in practical application are summarized,and it is pointed out that in the future,efficient and stable catalysts,non-iron-based enhanced Fenton-like technology and the combination/coupling technology of non-iron-based Fenton/Fenton-like technology with other processes are the main research areas.

关 键 词：铁基催化剂 芬顿/类芬顿系统 非铁类金属 氧化还原特性 

分 类 号：TQ151[化学工程—电化学工业]