不同无机纳米填料对PPS树脂材料的非等温结晶行为影响  

Influence of Different Inorganic Nanoparticles on Non-isothermal Crystallization Behaviour of PPS Composites

作　　者：梁军杰 程锋 黄永甫 朱寿权 陈培 仲双侠 倪金平 LIANG Junjie;CHENG Feng;HUANG Yongfu;ZHU Shouquan;CHEN Pei;ZHONG Shuangxia;NI Jinping(ZheJiang Shiny New Materials Co.,Ltd.,Wenzhou 325000,China)

机构地区：[1]浙江新力新材料股份有限公司,浙江温州325000

出　　处：《塑料工业》2022年第5期171-176,共6页China Plastics Industry

基　　金：温州工业科技项目(ZG2021007)。

摘　　要：将球状碳酸钙、片状滑石粉和纤维状凹凸棒土与聚苯硫醚(PPS)树脂熔融共混得到复合材料,采用差示扫描量热仪(DSC)对比了三种填料对复合材料的非等温结晶行为的影响,利用Jeziorny法和Mo法分析了复合材料的非等温结晶动力学,利用Friedman方程计算了复合材料在结晶前期和后期的非等温结晶活化能。结果表明,添加0.5%碳酸钙、滑石粉和凹凸棒土均促进PPS树脂结晶的发生,结晶速率作用效果依次为滑石粉>凹凸棒土>碳酸钙。Jeziorny方程、Mo方程和Friedman方程分析进一步表明三种填料促进PPS树脂的结晶。Polyphenylene sulfide(PPS)composites were prepared by melt blending with PPS and spherical calcium carbonate,flake talc and fibrous attapulgite,respectively.The influence of different inorganic nanoparticles on non-isothermal crystallization properties of PPS composites were studied by differential scanning calorimeter(DSC).The non-isothermal crystallization kinetics were analyzed by Jeziorny and Mo methods.The value of activation energy for crystallization of PPS composites in early stages and in later stages of crystallization were calculated by Friedman equation.The results show that 0.5%calcium carbonate,talc and attapulgite acting as efficient nucleating agents and the efficiency is decreased as follows:talc>attapulgite>calcium carbonate.The results from Friedman equation,Mo equation and Kissinger equation further verify that the addition of inorganic nanoparticles promotes the non-isothermal crystallization of PPS composites.

关 键 词：聚苯硫醚 无机纳米填料 非等温结晶 差示扫描量热法 

分 类 号：TQ326.5[化学工程—合成树脂塑料工业]