Interwoven nickel(II)-dimethylglyoxime nanowires in 3D nickel foam for dendrite-free lithium deposition  

作　　者：Tianyi Zhou Yanlu Mu Jianyang Wu Bing Zhong Chengkai Yang Qian Wang Wen Liu Henghui Zhou Peng Jiang 

机构地区：[1]CAS Key Laboratory of Standardization and Measurement for Nanotechnology,CAS Center for Excellence in Nanoscience,National Center for Nanoscience and Technology,Beijing 100190,China [2]College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China [3]University of Chinese Academy of Sciences,Beijing 100049,China [4]State Key Laboratory of Chemical Resource Engineering,College of Chemistry,Beijing Advanced Innovation Center for Soft Matter Science and Engineering,Beijing University of Chemical Technology,Beijing 100029,China [5]College of Materials Science and Engineering,Fuzhou University,Fuzhou 350108,China [6]Institute of Energy Innovation,College of Materials Science and Engineering,Taiyuan University of Technology,Taiyuan 030024,China

出　　处：《Chinese Chemical Letters》2022年第4期2165-2170,共6页中国化学快报（英文版）

基　　金：financially supported by PULEAD Technology Industry Co.,Ltd.,the Strategic Priority Research Program of Chinese Academy of Sciences (No. XDB36000000);the National Key Research and Development Program of China (No. 2016YFA0200904);the National Natural Science Foundation of China (Nos. 21771018and 21875004);the Natural Science Foundation of Beijing (No.2192018);National Natural Science Foundation of China-Regional Innovation Joint Exploration Fund (No. U19A2019);Beijing University of Chemical Technology (Start-up grant No. buctrc201901,BUCT, China)。

摘　　要：Metal skeletons,such as Nickel Foam(NF) has attracted worldwide interests as stable host for lithium metal anode because of its high stability,large specific surface area and high conductivity.However,most metal skeletons have lithophobic surface and uneven current distribution that result in sporadic lithium nucleation and uncontrolled dendrites growth.Herein,we describe a sequential immersing strategy to generate interwoven Nickel(Ⅱ)-dimethylglyoxime(Ni-DMG) nanowires at NF to obtain composite skeleton(NDNF),which can be used as an stable host for Li metal storage.The Ni-DMG has proved effective to realize uniform lithium nucleation and dendrite-free lithium deposition.Combing with the three dimensional(3 D) hierarchical porous structure,the composite host shows a significantly improved coulombic efficiency(CE) than pristine commercial nickel foam.Moreover,the corresponding Li‖Li symmetrical cells can run more than 700 h with low voltage hysteresis 22 mV at 1.0 mA/cm^(2),and Li@NDNF‖LiFePO;full-cell exhibits a high capacity retention of 82.03% at 1.0 C during 630 cycles.These results proved the effectiveness of metal-organic complexes in governing Li metal growth and can be employed as a new strategy for dendrite-free Li metal anode and safe Li metal batteries(LMBs).

关 键 词：Nickel(II)-dimethylglyoxime Nickel foam Metal-organic complex Uniform nucleation Dendrite-free 

分 类 号：TB383.1[一般工业技术—材料科学与工程] TM912[电气工程—电力电子与电力传动]