Catalyst-free Photochemical Bromination of Unprotected Aromatic Amino Acid Derivatives by Using a Rotating Ultraviolet Photoreactor  

作　　者：ZHANG Tingting LUO Pan LAI Can LIU Zheyi JIN Yan WANG Fangjun 

机构地区：[1]CAS Key Laboratory of Separation Sciences for Analytical Chemistry,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,P.R.China [2]University of Chinese Academy of Sciences,Beijing 100049,P.R.China

出　　处：《Chemical Research in Chinese Universities》2022年第2期505-509,共5页高等学校化学研究（英文版）

基　　金：supported by the National Key R&D Program of China(No.2019YFE0119300);the National Natural Science Foundation of China(Nos.32088101,91853101);the Grant from Chinese Academy of Sciences(No.ZDBSLY-SLH032);the Natural Science Foundation of Liaoning Province,China(No.2019-YQ-07);the Dalian Science and Technology Innovation Foundation,China (No.2019J11CY019);the Grant from Dalian Institute of Chemical Physics,CAS(No.DICP I202007).

摘　　要：Aromatic amino acid halides are valuable amino acid derivatives and fundamental building blocks that are used to various coupling reaction^1-3!,such as Heck,Suzuki and Ullmann reaction[4-7],and also important precursors of active natural products,pharmaceuticals and chiral auxiliaries[8-9].

关 键 词：CATALYST-FREE PHOTOCHEMISTRY BROMINATION 254 nm UV Unprotected aromatic amino acid derivative 

分 类 号：O62[理学—有机化学]