ZSM-5性能调控及其催化裂解石油轻组分研究进展  

Research progress on modification of ZSM-5 and its catalytic performance in cracking of light components in petroleum

作　　者：张莹 焦念明[2] 张凯伦 张香平 李涛 王慧[2,4] ZHANG Ying;JIAO Nian-ming;ZHANG Kai-lun;ZHANG Xiang-ping;LI Tao;WANG Hui(School of Chemical Engineering,Zhengzhou University,Zhengzhou 450001,China;Beijing Key Laboratoryof Ionic Liquids Clean Process,Institute of Process Engineering,Innovation Academy for Green Manufacture,Chinese Academy of Sciences,Beijing 100190,China;School of Chemical Sciences,University of Chinese Academy ofSciences,Beijing 100049,China;Zhengzhou Institute of Emerging Industrial Technology,Zhengzhou 450000,China)

机构地区：[1]郑州大学化工学院,河南郑州450001 [2]中国科学院绿色过程制造创新研究院中国科学院过程工程研究所离子液体清洁过程北京市重点实验室,北京100190 [3]中国科学院大学化学科学学院,北京100049 [4]郑州中科新兴产业技术研究院,河南郑州450000

出　　处：《应用化工》2022年第5期1433-1438,1444,共7页Applied Chemical Industry

基　　金：国家重点研发计划重点专项(2017YFC0212404);中国科学院洁净能源先导科技专项(XDA21031102);中国科学院绿色过程制造创新研究院自主部署项目(IAGM-2019-A12);中国科学院率先行动“百人计划”。

摘　　要：总结了ZSM-5酸性和孔结构的调控方法,包括:碱金属与碱土金属、过渡金属、稀土金属、非金属元素以及复合金属的掺入调控酸性;酸碱处理、水蒸气处理和引入模板剂等调控孔道结构,并综述了近年来改性分子筛在石油轻组分催化裂解中的应用进展。在此基础上,分析了ZSM-5分子筛在催化裂解过程中存在的主要问题,并对其发展前景进行了展望。This review summarizes the methods to modify the acidity and pore structure of ZSM-5:the introduction of alkali metals and alkaline earth metals,transition metals,rare earth metals,nonmetal elements and composite metals to regulate the acidity;treatment by acid-base,or water vapor treatment or introduction of a template agent to modify the channel structure.Moreover,the application of modified ZSM-5 in catalytic cracking of light components in petroleum in recent years is reviewed.Based on the current progress,the problems in catalytic cracking by ZSM-5 are analyzed,and the development prospects of ZSM-5 are given.

关 键 词：ZSM-5分子筛 性能调控 石油轻组分 催化裂解 

分 类 号：TQ530.51[化学工程—煤化学工程]