氢化物原子荧光光谱法测定水质样品中的硒  

Determination of selenium in water by hydride generation atomic fluorescence spectrometry

作　　者：魏嘉涛 阳辉伟 WEI Jiatao;YANG Huiwei(Guangdong Research Center for Geoanalysis,Guangzhou,Guangdong)

机构地区：[1]广东省地质实验测试中心,广东广州

出　　处：《江西化工》2022年第3期84-86,共3页Jiangxi Chemical Industry

摘　　要：本文对氢化物原子荧光光谱法测定水质样品中硒进行研究,优化了试样盐酸浓度、硼氢化钾浓度、仪器测定条件。在最优条件下进行验证实验,硒在(0.4-8.0)μg/L线性良好,相关系数r为0.9995,检出限为0.05μg/L,相对标准偏差RSD为0.99%-3.41%,加标回收率为89.3%-101%。该方法简单快速,且灵敏度、精密度和准确度高。hydride atomic fluorescence spectrometry determination of selenium in water samples was studied,the concentration of hydrochloric acid,potassium borohydride concentration of the sample,instrument determination conditions were optimized.The linear range of selenium was(0.4-8.0)μg/L,the correlation coefficient r was 0.9995,the limit of detection was 0.05μg/L,the relative standard deviations were 0.99%-3.41%,and the recoveries were 89.3%-101%.The method is simple and rapid,with high sensitivity,precision and accuracy.

关 键 词：氢化物原子荧光光谱法 硒 水 

分 类 号：O657.31[理学—分析化学] X832[理学—化学]