CO_(2)/C_(2)H_(4)耦合制备丙烯酸及其衍生物的研究进展  

Advances in the Production of Acrylic Acid and Its Derivatives by CO_(2)/C_(2)H_(4) Coupling

作　　者：朱有财 丁欣欣 孙莉[1] 刘振 Zhu Youcai;Ding Xinxin;Sun Li;Liu Zhen(School of Chemical Engineering,East China University of Science and Technology,Shanghai 200237)

机构地区：[1]华东理工大学化工学院,上海200237

出　　处：《有机化学》2022年第4期965-977,共13页Chinese Journal of Organic Chemistry

基　　金：浦江人才计划(No.18PJ1402500);国家自然科学基金(No.22171084)资助项目。

摘　　要：二氧化碳(CO_(2))不仅仅是一种温室气体,更是一种重要的、有效的碳一资源,其来源丰富、无毒、无污染、不易燃烧,可用于生产有机化学品、材料、糖类等.由于CO_(2)分子中的碳处于最高氧化态,且其分子具有热力学和动力学惰性,因此人们不断探索新型反应途径,以及新型的催化体系来有效资源化利用CO_(2).近年来,利用各种不饱和烃类,在过渡金属催化剂协助下催化CO_(2)与烯烃生成不饱和羧酸及其衍生物引起了极大关注.其中,催化CO_(2)/C_(2)H_(4)耦合反应制备丙烯酸及其衍生物因其原子经济性而备受瞩目.以镍系催化体系为主的过渡金属催化CO_(2)/C_(2)H_(4)偶联反应是CO_(2)化学转化与高值利用非常重要的研究热点之一.综述了近年来CO_(2)/C_(2)H_(4)偶联反应的最新进展,对相应的催化反应机理进行了评述.从多个角度对各位学者的研究进行分析比较,并对各研究方向进行了展望.Carbon dioxide(CO_(2))is not just a greenhouse gas,but also an important and effective one-carbon resource,which is abundant in nature and can be used to produce organic chemicals,materials,and sugars etc.CO_(2) is thermodynamically and kinetically inert because the carbon atom in CO_(2) molecule is in its highest oxidation state.In the past decades,several catalytic systems have been developed for the utilization of CO_(2).The catalytic conversion of CO_(2) to unsaturated carboxylic acids and their derivatives has attracted great attention.Among them,the so-called“dream reaction”of coupling CO_(2)/C_(2)H_(4) is 100%atom efficient.Transition metal-based catalysts are developed for catalytic transformation of CO_(2)/C_(2)H_(4) into acrylic acid and its derivatives,including Ni,Pd,Fe,and Ru etc.In addition,the additives play an important role in improving the catalyst performance.In this review,the recent advances on transition metal complex catalyzed CO_(2)/C_(2)H_(4) coupling reaction are summarized on the basis of catalyst activity and reaction mechanisms,including both the experiment and theoretical calculation.Furthermore,the challenges and perspectives in the catalytic transformation of CO_(2)/C_(2)H_(4) are also discussed.

关 键 词：二氧化碳 丙烯酸 耦合反应 反应机理 

分 类 号：TQ225.131[化学工程—有机化工] O643.36[理学—物理化学]