基于四配位硼的1,2-迁移反应研究进展  

Recent Progress on 1,2-Metallate Shift Reactions Based on Tetracoordinate Boron Intermediates

作　　者：张锋 周鹿 杨凯 宋秋玲 Zhang Feng;Zhou Lu;Yang Kai;Song Qiuling(Key Laboratory of Molecule Synthesis and Function Discovery,Fujian Province University,College of Chemistry,Fuzhou University,Fuzhou 350108;Institute of Next Generation Matter Transformation,College of Materials Science Engineering,Huaqiao University,Xiamen,Fujian 361021)

机构地区：[1]福州大学化学学院有机合成与功能福建省高校重点实验室,福州350108 [2]华侨大学材料学院新一代物质转化研究所,福建厦门361021

出　　处：《有机化学》2022年第4期1013-1032,共20页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(Nos.21772046,2193103)资助项目。

摘　　要：有机硼化合物是合成方法学中重要且通用的合成骨架.由于其独特的性质,它们在有机合成中表现出巨大的价值.有机硼化合物具有丰富的转化能力,近年来,由于其迁移反应高效、反应条件温和而受到了化学家们的广泛关注,用于快速构建各种碳碳键和碳杂键.本篇综述根据不同的反应条件和键的形成,系统总结了近年来基于四配位硼中间体的1,2-迁移反应.Organoboron compounds are important and versatile synthetic building blocks in synthetic chemistry.Owing to the unique characteristics,they manifest great value in organic synthesis.In view of the versatile transformations,migration reactions of organoboron compounds have attracted great attention from chemists in recent years due to their high efficiency and mild reaction conditions,which are widely utilized for rapid constructions of carbon-carbon and carbon-heteroatom bonds.Recent progress on 1,2-migration reactions based on tetracoordinate boron intermediates is summarized according to various reaction conditions and bond formations.

关 键 词：碳碳键和碳杂键 四配位硼中间体 1 2-迁移反应 

分 类 号：O627.31[理学—有机化学]