SO_(2)与N,N-二烯丙基胺盐环化共聚物的应用及研究进展  

Application and research progress in cyclopolymerization of N,N-diallylamine and SO_(2)

作　　者：王丽媛 李珍 刘毅 支云飞 陕绍云[2] 苏红莹[2] WANG Liyuan;LI Zhen;LIU Yi;ZHI Yunfei;SHAN Shaoyun;SU Hongying(Tin Chemical Company Limited of Yunnan Tin Co. Ltd.,Gejiu 661000,China;Faculty of Chemical Engineering,Kunming University of Science and Technology,Kunming 650504,China)

机构地区：[1]云南锡业锡化工材料有限责任公司,云南个旧661000 [2]昆明理工大学化学工程学院,云南昆明650504

出　　处：《化工科技》2022年第2期77-82,共6页Science & Technology in Chemical Industry

基　　金：国家自然科学基金项目(21766016,22068023);云南省“万人计划”基金项目(YNWR-QNBJ-2018-198);昆明市科学技术局科技计划基金项目(2019-1-G-25318000003480)。

摘　　要：SO_(2)与N,N-二烯丙基胺共聚物具有聚砜及胺基聚合物的结构,在添加剂、凝聚剂、增稠剂、催化剂和杀菌剂等方面有重要的研究价值和广阔的应用前景。对SO_(2)与N,N-二烯丙基胺盐通过Butler环化共聚机理制备新型材料及其产物性能、应用领域进行了系统综述,通过与不同N,N-二烯丙基胺盐的环化共聚产物性能及应用领域进行对比,进一步分析了聚合物主链上SO_(2)的嵌入对聚合效率及性能的影响规律,为今后SO_(2)共聚领域的发展提供指导和帮助。Copolymers of N,N-diallylamine and SO_(2) have some special structures of polysulfone and ammonium polymer,which have been applied in additive,coagulating agent,thickening agent,catalyst,fungicides and so on.Copolymerization of N,N-diallylamine and SO_(2) has an important research value and broad application prospects.This paper summarized the copolymerization of N,N-diallylamine and SO_(2) by Butler′s cyclopolymerization mechanism in recent years.By comparing with the performances of the cyclopolymers with the different structures,the effects of SO_(2) on polymerization efficiency and performance were further analyzed.We wish this review could be helpful and guided to SO_(2) copolymerization.

关 键 词：SO_(2) N N-二烯丙基胺盐 Butler式环化共聚 

分 类 号：TH3[机械工程—机械制造及自动化]