Photochemical defluorinative functionalization of α-polyfluorinated carbonyls via spin-center shift  

作　　者：Zele Chen Jiarong Chen Jun Xuan 

机构地区：[1]Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials and Key Laboratory of Functional Inorganic Materials of Anhui Province,College of Chemistry&Chemical Engineering,Anhui University,Hefei 230601,China [2]CCNU-uOttawa Joint Research Centre,College of Chemistry,Central China Normal University,Wuhan 430079,China

出　　处：《Chinese Chemical Letters》2022年第6期2763-2764,共2页中国化学快报（英文版）

摘　　要：Organic molecules containing gem–difluoromethylene unit are one of the most important classes of compounds that have various valuable applications ranging from drug discovery to material science [1]. Not surprisingly, numerous strategies have been developed towards the synthesis of these target organofluorine compounds. Within this research area, direct C–F bond cleavage of cheap and readily accessible polyfluorinated compounds represents one of the most potentially powerful methods to access diverse gem–difluoromethylene skeletons.

关 键 词：FLUORINE SKELETON readily 

分 类 号：O621.25[理学—有机化学]