A facile approach to fabricating graphene/waterborne epoxy coatings with dual functionalities of barrier and corrosion inhibitor  

作　　者：Suyun Liu Xuewan Wang Qi Yin Xiongzhi Xiang Xian-Zhu Fu Xian-Zong Wang Jing-Li Luo 

机构地区：[1]Shenzhen Key Laboratory of Polymer Science and Technology,Guangdong Research Center for Interfacial Engineering of Functional Materials,College of Materials Science and Engineering,Shenzhen University,Shenzhen 518060,China [2]Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province,College of Optoelectronic Engineering,Shenzhen University,Shenzhen 518060,China [3]State Key Laboratory of Solidification Processing,Center of Advanced Lubrication and Seal Materials,Northwestern Polytechnical University,Xi’an 710072,China

出　　处：《Journal of Materials Science & Technology》2022年第17期263-276,共14页材料科学技术（英文版）

基　　金：financially supported by the National Natural Science Foundation of China(Nos.52001214 and 51902204);the China Postdoctoral Science Foundation(No.2020M672796);the Bureau of Industry and Information Technology of Shenzhen(No.201901171518);the Shenzhen Science and Technology Program(No.JSGG20191129141016881);the technical support provided by Instrumental Analysis Center of Shenzhen University(Xili Campus)and the Shiyanjia lab(www.shiyanjia.com)。

摘　　要：A facile and environmentally-friendly method is developed to prepare graphene/waterborne epoxy(WEP)composite coatings.The graphene nanosheets are produced with electrochemical-exfoliation in the solution containing surfactants,cetyl trimethyl ammonium bromide(CTAB)and sodium dodecyl sulfate(SDS).The nanosheets containing solution thus formed are subjected to a quick dialysis and then directly used as a diluent for WEP without any further treatment.This preparation method overcomes the commonly identified problems of aggregations and‘corrosion promotion’effect associated with graphene,and increases the impedance of the composite coatings by more than two orders of magnitude.The analysis of anticorrosion performance suggested that the presence of surfactants not only improves the dispersibility of graphene nanosheets but also endows the composite coatings with both barrier and corrosion inhibition capabilities.The strategy reported herein may pave the path to the large-scale production of graphene anticorrosion coatings.

关 键 词：Electrochemical-exfoliation graphene Waterborne epoxy coatings ANTICORROSION Inhibition 

分 类 号：TG174.4[金属学及工艺—金属表面处理]