Tandem catalysis on adjacent active motifs of copper grain boundary for efficient CO_(2) electroreduction toward C2 products  

作　　者：Tao Luo Kang Liu Junwei Fu Shanyong Chen Hongmei Li Junhua Hu Min Liu 

机构地区：[1]Hunan Joint International Research Center for Carbon Dioxide Resource Utilization,State Key Laboratory of Powder Metallurgy,School of Physics and Electronics,Central South University,Changsha 410083,Hunan,China [2]School of Materials Science and Engineering,Zhengzhou University,Zhengzhou 450002,Henan,China

出　　处：《Journal of Energy Chemistry》2022年第7期219-223,I0006,共6页能源化学（英文版）

基　　金：the National Natural Science Foundation of China(21872174,22002189,U1932148);the International Science and Technology Cooperation Program(2017YFE0127800,2018YFE0203402);the Hunan Provincial Science and Technology Program(2017XK2026);the Hunan Province Key Field R&D Program(2020WK2002);the Hunan Provincial Natural Science Foundation of China(2020JJ2041,2020JJ5691);the Shenzhen Science and Technology Innovation Project(JCYJ20180307151313532);the Fundamental Research Funds for the Central Universities of Central South University;。

摘　　要：Copper (Cu) is a special electrocatalyst for CO_(2) reduction reaction (CO_(2)RR) to multi-carbon products.Experimentally introducing grain boundaries (GBs) into Cu-based catalysts is an efficient strategy to improve the selectivity of C^(2+) products.However,it is still elusive for the C^(2+) product generation on Cu GBs due to the complex active sites.In this work,we found that the tandem catalysis pathway on adjacent active motifs of Cu GB is responsible for the enhanced activity for C^(2+)production by first principles calculations.By electronic structure analysis shows,the d-band center of GB site is close to the Fermi level than Cu(100) facet,the Cu atomic sites at grain boundary have shorter bond length and stronger bonding with*CO,which can enhance the adsorption of*CO at GB sites.Moreover,CO_(2)protonation is more favorable on the region Ⅲ motif (0.84 e V) than at Cu(100) site (1.35 e V).Meanwhile,the region Ⅱ motif also facilitate the C–C coupling (0.72 e V) compared to the Cu(100) motif (1.09 e V).Therefore,the region Ⅲ and Ⅱ motifs form a tandem catalysis pathway,which promotes the C^(2+)selectivity on Cu GBs.This work provides new insights into CO_(2)RR process.

关 键 词：Cu(100)facet Grain boundary CO_(2)electroreduction C2+products Tandem catalysis 

分 类 号：TQ426[化学工程] X701[环境科学与工程—环境工程]