偶氮苯基两亲性聚合物的自组装行为研究进展  

Research Progress in Self-Assembly of Azobenzene-Based Amphiphilic Polymer

作　　者：李婉冰 张海波[1] 张成领 商士斌[1] 宋湛谦 Li Wanbing;Zhang Haibo;Zhang Chengling;Shang Shibin;Song Zhanqian(Institute of Chemical Industry of Forest Products,CAF,National Engineering Lab.for Biomass Chemical Utilization,Key Lab.of Chemical Engineering of Forest Products,National Forestry and Grassland Administration,Key Lab.of Biomass Energy and Material,Jiangsu Province,Nanjing,210042;Co-Innovation Centerof Efficient Processing and Utilizationof Forestry Resources,Nanjing Forestry University,Nanjing,210037;Jinan AutomobileTest Centre Co.,Ltd,Jinan,250102)

机构地区：[1]中国林业科学研究院林产化学工业研究所,生物质化学利用国家工程实验室,国家林业和草原局林产化学工程重点实验室,江苏省生物质能源与材料重点实验室,南京210042 [2]南京林业大学,江苏省林业资源高效加工利用协同创新中心,南京210037 [3]济南汽车检测中心有限公司,南京250102 [4]中国工程院

出　　处：《化学通报》2022年第7期781-789,共9页Chemistry

基　　金：国家自然科学基金项目(31901261)资助。

摘　　要：偶氮苯基两亲性聚合物结合了偶氮苯基团的光响应、酶响应、主客体识别特性和两亲性聚合物的自组装特性,能够在选择性溶剂中发生聚合物可控自组装行为,这使得其在药物控释、纳米技术和生物医学材料等领域受到了广泛的关注。本文从结构类型和合成方法出发,综述了新型偶氮苯基两亲性聚合物在溶液中的自组装研究进展,并对该领域的发展前景进行了展望。The azobenzene-based amphiphilic polymer combines the light-, enzyme-and host-guest responsive characteristics of the azobenzene group and the self-assembly characteristics of the amphiphilic polymer, can produce controllable self-assembly behavior of polymer in selective solvent, which makes it attract extensive attention in the controlled release of drugs, nanotechnology and biomedical materials fields. In this paper, the research progress of self-assembly behavior of azobenzene-based amphiphilic polymer in solution is reviewed starting from the structure types and synthesis methods, and the development prospect of this field is also prospected.

关 键 词：偶氮苯 两亲性聚合物 自组装 刺激响应性 

分 类 号：TQ317[化学工程—高聚物工业] O641.3[理学—物理化学]