Metal-Oxo Cluster Catalysts for Photocatalytic Water Splitting and Carbon Dioxide Reduction  

作　　者：Qing Lan Sujuan Jin Bohan Yang Qiang Zhao Chaolei Si Haiquan Xie Zhiming Zhang 

机构地区：[1]Engineering Technology Research Center of Henan Province for Solar Catalysis,College of Chemistry and Pharmaceutical Engineering,Nanyang Normal University,Nanyang 473061,China [2]Institute of New Energy Materials and Low Carbon Technology,Tianjin University of Technology,Tianjin 300384,China

出　　处：《Transactions of Tianjin University》2022年第3期214-225,共12页天津大学学报（英文版）

基　　金：supported by National Natural Science Foundationof China(Grant No.21671113);the Science and Technology of Henan province in 2018(No.182102310873);2019 Special Project of Nanyang Normal University(Nos.2019ZX009 and 2019QN011);Project of Young Backbone Teachers in Colleges and Universities of Henan Province(No.2020GGJS180);2019 Henan Higher Education Teaching Reform Research and Practice Project(No.2019SJGLX093Y).

摘　　要：Photocatalytic water splitting and carbon dioxide photoreduction are considered eff ective strategies for alleviating the energy crisis and environmental pollution.Polynuclear metal-oxo clusters possess excellent electron storage/release ability and unique catalytic properties via intermetallic synergy,which enables them with great potential in environmentally friendly photosynthesis.Importantly,metal-oxo clusters with precise structure can not only act as high-effi ciency catalysts but also provide well-defi ned structural models for exploring structure-activity relationships.In this review,we systematically sum-marize recent progress in the catalytic application of polynuclear metal-oxo clusters,including polyoxometalate clusters,low-cost transition metal clusters,and metal-oxo-cluster-based metal-organic frameworks for water splitting and CO_(2)reduction.Furthermore,we discuss the challenges and solutions to the problems of polynuclear metal-oxo clusters in photocatalysis.

关 键 词：Water splitting Carbon dioxide photoreduction PHOTOCATALYSIS Polynuclear metal-oxo clusters Polyoxomatalate 

分 类 号：O643.36[理学—物理化学]