Fe/Zr共掺杂纳米ZnO催化降解罗丹明B性能研究  被引量:1

Study on Catalytic Degradation of Rhodamine B by Fe/Zr Co-doped Nano ZnO

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作  者:王雷 刘东升 Wang Lei;Liu Dongsheng(Kaili University,Qiandongnan,Guizhou 556011,China)

机构地区:[1]凯里学院,贵州黔东南556011

出  处:《绿色科技》2022年第14期270-273,共4页Journal of Green Science and Technology

基  金:国家自然科学基金(编号:3176019);黔东南州科技计划项目(编号:黔东南科合J字[2021]40号);凯里学院博士启动项目(编号:BS201814)。

摘  要:采用溶胶-凝胶法制备了纳米ZnO及1%、2%Fe/Zr共掺杂量的ZnO,使用扫描电镜对制备的纳米材料进行了形貌观察,采用紫外分光光度计测试了纳米材料的吸收光谱及其对罗丹明B的光催化降解性能。结果表明:随着Fe/Zr共掺杂量的增加,纳米ZnO显示出较明显的团聚倾向,而且颗粒增大;同时发现,在催化时间较短时,掺杂对纳米ZnO降解罗丹明B的影响不明显,但随着催化时间增加,Fe/Zr共掺杂后的降解效果要优于纯纳米ZnO,尤其1%Fe/Zr共掺杂纳米ZnO对有机污染物罗丹明B的综合催化降解性能优势明显,降解效果更好。Nano ZnO and ZnO doped with 1%and 2%Fe/Zr were prepared by sol-gel method.The morphology of the prepared nanomaterials was observed by SEM.The absorption spectra of the nanomaterials and their photocatalytic properties for Rhodamine B were measured by UV spectrophotometer.The results show that with the increase of Fe/Zr co-doping,nano ZnO shows a tendency of agglomeration and the particles increase;At the same time,it is found that the degradation effect of nano ZnO on Rhodamine B is not significantly affected by doping when the catalytic time is short,but with the increase of catalytic time,the degradation effect of Fe/Zr Co-doped nano ZnO is better than that of pure nano ZnO.Especially 1%Fe/Zr Co-doped nano ZnO has obvious comprehensive catalytic degradation performance and better degradation effect on organic pollutant rhodamine B.

关 键 词:纳米ZNO Fe/Zr共掺杂 光催化 罗丹明B 

分 类 号:O643[理学—物理化学]

 

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