评价表面活性剂溶液泡沫性能的方法—真球气泡法  

Method of Evaluating the Foaming Properties of Surfactant Solutions—Real Sphere Bubble Method

作　　者：焦陈斯帆 郑少波 许鹏军 王炜[2] Hiromichi Takebe Kusuhiro Mukai 余仲达 JIAO Chen-Si-Fan;ZHENG Shao‑Bo;XU Peng-Jun;WANG Wei;HIROMICHI Takebe;KUSUHIRO Mukai;YU Zhong-Da(Department of Material Science and Engineering,Shanghai University,State Key Lab of Metallurgy and Preparation of High Quality Special Steel,Shanghai 200072,China;Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education,Wuhan University of Science and Technology,Wuhan 430081,China;Ehime University,Matsuyama 9008267,Japan;Kyushu Institute of Technology,Kyushu 8048550,Japan)

机构地区：[1]上海大学材料科学与工程学院,省部共建高品质特殊钢冶金与制备国家重点实验室,上海200072 [2]武汉科技大学湖北省冶金二次资源工程技术研究中心,武汉430081 [3]爱媛大学,松山790‑0826,日本 [4]九州工业大学,九州804‑8550,日本

出　　处：《应用化学》2022年第7期1108-1118,共11页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金(No.51974212);国家自然科学基金委员会-中国宝钢钢铁集团有限公司钢铁联合研究基金项目(No.U1760101)资助。

摘　　要：通过真球气泡法测定了不同价数和浓度的无机盐体系下十二烷基硫酸钠(SDS)表面活性剂溶液的表面张力和表面扩展黏度;通过Ross-Miles法测定了相应同一溶液的发泡力和泡沫稳定性;结果表明:SDS溶液的表面张力值随着各种无机盐浓度的增加而减小至不变,此时的无机盐浓度作为相对浓度100%来考察时,发现临界胶束浓度(CMC)值与添加盐的种类无关,只随无机盐的相对浓度的增加而减少;即CMC值随着无机盐的相对浓度的增加从不含无机盐时的8.3 mmol/L均收敛至最小值3.0 mmol/L;表面张力值和对应的发泡力值呈负线性关系,由此推断表面张力值可以评价发泡力;表面扩展黏度值和对应的泡沫稳定性值呈正线性关系,由此推断表面扩展黏度可以评价泡沫稳定性;无机盐种类对SDS表面活性剂发泡力和泡沫稳定性的影响力随阳离子价数(Na^(+)、Cu^(2+)、Fe^(3+))增加而增加。The surface tension and surface expansion viscosity of sodium dodecyl sulfate(SDS)surfactantsolutions of different valences and concentrations of inorganic salt systems were measured by the true sphericalbubble method.The foaming power and foam stability of the same solution were measured by the Ross-Milesmethod.The following results are obtained:(Ⅰ)The surface tension of the SDS solution decreases with theincrease of inorganic salt concentrations until a constant value at certain concentration which is set as as arelative concentration of 100%.It is found that the critical micelle concentration(CMC)value has nothing todo with the type of added salt,but only decreases with the increase of the relative concentration of inorganicsalt,i.e.,the CMC value increases with the inorganic salt.The increase in the relative concentration of,from 8.3 mmol/L without inorganic salt,converges to the minimum value of 3.0 mmol/L;(Ⅱ)The surface tensionand the corresponding foaming force are in a negative linear relationship,and the surface tension is inferred.The foaming power can be evaluated as that,the surface expansion viscosity and the corresponding foamstability value have a positive linear relationship,from which it is inferred that the surface expansion viscositycan evaluate the foam stability;(Ⅲ)The foaming power and foam stability of SDS surfactants increases withthe valence of cations(Na,Cu,Fe).

关 键 词：无机盐 表面张力 表面扩展粘度 临界胶束浓度 发泡力 泡沫稳定性 

分 类 号：O648[理学—物理化学]