Entropy-driven phase regulation of high-entropy transition metal oxide and its enhanced high-temperature microwave absorption by in-situ dual phases  

作　　者：Guohao Dai Ruixiang Deng Xiao You Tao Zhang Yun Yu Lixin Song 

机构地区：[1]Key Laboratory of Inorganic Coating Materials CAS,Shanghai Institute of Ceramics,Chinese Academy of Sciences,Shanghai 200050,China [2]State Key Laboratory of High Performance Ceramics&Superfine Microstructure,Shanghai Institute of Ceramics,Chinese Academy of Sciences,Shanghai 200050,China [3]School of Physical Science and Technology,ShanghaiTech University,Shanghai 201210,China [4]Center of Materials Science and Optoelectronics Engineering,University of Chinese Academy of Sciences,Beijing 100049,China

出　　处：《Journal of Materials Science & Technology》2022年第21期11-21,共11页材料科学技术（英文版）

基　　金：financially supported by the Shanghai Sailing Program(No.21YF1454600)。

摘　　要：High-temperature microwave absorbers are significant for military equipment which experiences severe aerodynamic heat.In this work,high-entropy oxide(HEO)(FexCoNiCrMn)mOn with excellent high-temperature microwave absorption is studied.Driven by the effect of entropy,the composition of the oxide can be transformed from spinel-type phase(FexCoNiCrMn)_(3)O_(4) to corundum-type phase(FexCoNiCrMn)2O3 with the increasing content of iron.Only spinel-type or corundum-type structure composes the oxide when x≤3 or x≥5.But in-situ dual phases can coexist when x equals 4 during phase transition.Interestingly,obliged to abundant heterogeneous interfaces and crystal defects in the dual-phase HEO,magnetic property,dielectric polarization,and microwave loss ability are all well enhanced.The Smith chart analysis demonstrates the impedance matching condition is well improved due to the enhanced loss ability.These findings pave a new way for the adjustment of electromagnetic properties of HEO by entropy-driven phase regulation.Meanwhile,the dual-phase absorber can achieve better than 90%absorption in 9.6-12.4 GHz at 800℃ with a thickness of 2.6 mm,a low thermal diffusivity of 0.0038 cm^(2)/s at 900℃,and excellent high-temperature stability,which indicates it’s promising as a high-temperature microwave absorber.

关 键 词：High entropy oxide In-situ dual phases High temperature Microwave absorption 

分 类 号：TB34[一般工业技术—材料科学与工程]