Highly stable aqueous phase black phosphorus quantum dots with enhanced fluorescence property  

作　　者：Yingli Ma Xiaoguang Xu Xiaoshuang Zhang Mayifei Rong Liying Lu Yan Li Wenhao Dai Hongwu Du Yong Jiang 

机构地区：[1]School of Materials Science and Engineering,University of Science and Technology Beijing,Beijing 100083,China [2]School of Chemistry and Biological Engineering,University of Science and Technology Beijing,Beijing 100083,China

出　　处：《Journal of Materials Science & Technology》2022年第21期50-57,共8页材料科学技术（英文版）

基　　金：partially supported by the National Key Research and Development Program of China(No.2019YFB2005801);the National Natural Science Foundation of China(Nos.51671019,52061135205,51971024,51731003,51971023,51927802);the Beijing Natural Science Foundation Key Program(No.Z190007)。

摘　　要：Black phosphorus quantum dots(BPQDs)are a kind of outstanding optical material due to the tunable band structure.However,their fluorescence property and stability are obviously weakened in the aqueous phase,which extremely restricts the development of BPQDs.Here,we propose a new method to prepare stable BPQDs in an aqueous solution directly with high absolute fluorescence quantum yield.Aqueous phase BPQDs are synthesized by liquid exfoliation and hydrothermal with NH_(2)-polyethylene glycol(PEG)-NH_(2) as the modification agent to protect the BPQDs,which have high stability more than six months.In addition,NH_(2)-PEG-NH_(2) is also a surface passivation agent to enhance the emission of BPQDs by forming P-N bonds,which is confirmed by an absolute fluorescent quantum yield of 11.5%.Moreover,BPQDs show excellent resistance to a strong acid environment and high ionic strengths except for Fe^(3+).Therefore,the BPQDs are a kind of highly selective and linear response fluorescence probe for Fe^(3+).Considering the good biocompatibility of BPQDs,they are employed as cell fluorescent label probes and show excellent fluorescence imaging contrast.Based on the unique structural stability and fluorescence performance in the aqueous phase,BPQDs are potential candidates for Fe^(3+)detection and optical bio-imaging.

关 键 词：Black phosphorus Quantum dots FLUORESCENCE Iron detection Cell imaging 

分 类 号：TB383.1[一般工业技术—材料科学与工程] O657.3[理学—分析化学]