有序介孔材料:历史、现状与发展趋势  

Ordered Mesoporous Materials:History,Progress and Perspective

作　　者：郭程 张威[1,2] 唐云 GUO Cheng;ZHANG Wei;TANG Yun(College of Chemistry and Materials,Fudan University,Shanghai 200433,China;Zhuhai Fudan Innovation Institute,Zhuhai 519000,China)

机构地区：[1]复旦大学化学与材料学院,上海200433 [2]珠海复旦创新研究院,珠海519000

出　　处：《高等学校化学学报》2022年第8期201-217,共17页Chemical Journal of Chinese Universities

基　　金：国家重点研发计划项目(批准号:2018YFA0209401,2017YFA0207303);国家自然科学基金(批准号:22105041,21733003,22088101);中国博士后科学基金(批准号:2020TQ0064,2020M680051);广东省自然科学基金(批准号:2021A1515010108)资助。

摘　　要：有序介孔材料是指孔径在2~50 nm之间的多孔材料,是一类具有均匀孔径、高有序度纳米孔道和高比表面积的新材料.在过去30年里,有序介孔材料的研究取得了长足的进步,在可控合成、结构设计和调控及功能化等方面形成了系统的理论.同时,其应用领域也不断被拓展,包括能源存储与转化、催化、生物医药和传感等方面.本文首先回顾了有序介孔材料的发展历史,简要介绍发展过程中“里程碑式”的研究工作;然后根据构效关系总结了其在不同领域应用的最新进展;最后讨论了有序介孔材料领域进一步发展所面临的挑战与机遇,并对未来前景进行了展望.Ordered mesoporous materials with pore diameters ranged from 2 nm to 50 nm possess ordered mesostruc⁃tures,high surface areas,large pore volumes and tunable compositions,which have received great research interests in many fields.In the past decades,the precise synthesis,rational design,and controllable functionalization of ordered mesoporous materials have made great progresses,thereby laying a solid foundation for the practical applica⁃tions,including energy storage and conversion,catalysis,biomedicine,and sensing.This review first summarizes the development history of ordered mesoporous materials comprehensively,and the milestones in this field are reviewed in detail.After that,based on the structure-property relationship,the latest progresses of ordered mesoporous materials in emerging fields,such as energy,catalysis and biomedicine are overviewed.In the last,the research challenges in this field are presented and the future perspectives are outlined.

关 键 词：有序介孔材料 发展历史 能源存储与转化 生物医药 传感 

分 类 号：O641[理学—物理化学]