松香基双子表面活性剂合成及应用进展  

Progress in synthesis and application of rosin based gemini surfactants

作　　者：赵淑芬 郑丹苗 刘华溪 宋松林 陈站 杨泞源 韦星船[1] Shufen Zhao;Danmiao Zheng;Huaxi Liu;Songlin Song;Zhan Chen;Ningyuan Yang;Xingchuan Wei(School of Chemistry and Chemical Engineering,Guangzhou University,Guangzhou,Guangdong 510006,China;Qingyuan Kolinda New Materials Co.,Ltd.,Qingyuan,Guangdong 511500,China)

机构地区：[1]广州大学化学化工学院,广东广州510006 [2]清远市柯林达新材料有限公司,广东清远511500

出　　处：《日用化学工业》2022年第8期892-903,共12页China Surfactant Detergent & Cosmetics

基　　金：清远市科技计划项目(2019DZX023,2020DZX015);广州大学大学生创新训练项目(XJ202011078035);广东省研究生教育创新计划项目(2019SFKC41)。

摘　　要：松香是一种重要的天然化工原料,无毒、可再生,应用十分广泛。松香系列双子表面活性剂主要是以松香酸及其衍生物合成,属于生物基表面活性剂,具有天然松香绿色环保、良好的表面性能以及良好的生物降解性能等特点,其分子设计合成、性能检测及应用开发成为研究热点。根据松香基双子表面活性剂亲水基的解离性质不同,按照阴离子型、阳离子型、两性型和非离子型对松香基双子表面活性剂进行分类,概括了近年来松香基双子表面活性剂的研究进展,探讨了松香基双子表面活性剂的各种性能,简述了各类松香基双子表面活性剂的合成方法、性能特点及应用领域,展望了松香基型双子表面活性剂的发展趋势。It is necessary to develop environment-friendly and sustainable surfactants owing to the more and more attention to environment,ecology and sustainable development and the rapid reduction of petroleum resources.Rosin is an important natural chemical raw material,which is non-toxic,renewable,and widely used.Rosin-based gemini surfactants are mainly synthesized from abietic acid and its derivatives,which belong to bio-based surfactants.They are green,environment-friendly and have good surface activity and good biodegradability.Their design and synthesis,performance test and application development have become research hotspots.According to the different properties of headgroups,rosin-based gemini surfactants are classified into anionic,cationic,amphoteric and non-ionic types.In this review,the research progress of rosin-based gemini surfactants in recent years is summarized.The performance of rosinbased gemini surfactants is discussed.The synthetic methods,performance characteristics and application of various rosin-based gemini surfactants are briefly described.The development trend of rosin-based gemini surfactants is also prospected.

关 键 词：松香基 双子表面活性剂 绿色 合成 应用 

分 类 号：TQ423[化学工程]