热致相分离法制备微孔膜的稀释剂研究进展  

Research progress of diluents for the preparation of microporous membranes by thermally induced phase separation

作　　者：王玉杰[1,2] 毛恒 赵之平 WANG Yujie;MAO Heng;ZHAO Zhiping(Sinopec(Beijing)Chemical Research Institute Co.Ltd.,Beijing 100013,China;School of Chemistry and Chemical Engineering,Beijing Institute of Technology,Beijing 102488,China)

机构地区：[1]中石化(北京)化工研究院有限公司,北京100013 [2]北京理工大学化学与化工学院,北京102488

出　　处：《膜科学与技术》2022年第4期163-172,共10页Membrane Science and Technology

基　　金：国家自然科学基金项目(21736001和22008008);中石化(北京)化工研究院科技项目(15-17ZS0526);北京理工大学青年教师学术启动计划项目(202211005)。

摘　　要：热致相分离(TIPS)法制备的微孔膜因具有孔隙率高、渗透通量大、孔径分布窄、孔径可调、机械强度高等优势而备受关注。在TIPS法制备微孔膜过程中,稀释剂的选择对相分离过程尤为重要,直接决定了微孔膜的结构与形态。本文综述了稀释剂在TIPS法制备微孔膜中的研究进展。首先介绍了稀释剂的筛选依据;其次重点阐述了稀释剂种类对所制微孔膜的形貌、结构与性能的影响;最后指出,通过结合机器学习、深度学习等技术构建精准稀释剂选择的理论模型,开发绿色、高效的稀释剂是TIPS法制备微孔膜研究的重点方向之一.Microporous membranes prepared by thermally induced phase separation(TIPS)have attracted much attention due to their high porosity,large permeation flux,narrow pore size distribution,adjustable pore size,and high mechanical strength.In the preparation of microporous membranes by TIPS method,the selection of diluent is particularly important for the phase separation process,which directly determines the structure and morphology of the microporous membranes.In this study,the research progress of diluents in the preparation of microporous membranes by thermally induced phase separation is reviewed.Firstly,the selection principle of the diluent is introduced.And then,the effects of different diluents on the morphology,structure and performance of the prepared microporous membrane are elaborately elucidated.Finally,it is pointed out that combining the machine learning,deep learning,and other technologies to build a precise theoretical model for diluent selection,the development of green and efficient diluents is one of the key research directions on the microporous membrane preparation by TIPS method.

关 键 词：热致相分离 微孔膜 稀释剂 膜结构 筛选依据 

分 类 号：TQ028.8[化学工程]