Effect of Electrolyte Nature on Micellar Soft-Template Electropolymerization in Organic Solvent to Form Nanoporous Polymer Films with a Bioinspired Strategy  

作　　者：Caroline Fradin Francois Orange Sonia Amigoni Frédéric Guittard Thierry Darmanin 

机构地区：[1]NICE Lab,UniversitéCote d’Azur,06100 Nice,France [2]Centre Commun de Microscopie Appliquée(CCMA),UniversitéCote d’Azur,06100 Nice,France

出　　处：《Journal of Bionic Engineering》2022年第2期547-553,共7页仿生工程学报（英文版）

基　　金：supported by CNRS GDR 2088《BIOMIM》.

摘　　要：Here,using a bioinspired approach,the soft-template electropolymerization of naphtho[2,3-b]thieno[3,4-e][1,4]dioxine(NaphDOT)was conducted in dichloromethane with different water content,and using different supporting electrolytes.The role of the electrolytes in the formation of reverse micelles that constitutes the soft template is investigated.The reverse micelles stabilized by the electrolyte and the monomer were observed by TEM and related to the various porous nanostructures of the obtained polymer films.We show that the nature of the electrolyte is not only fundamental for the formation of reverse micelles and thus porous nanostructures,but also plays a huge role in the good deposition of the oligomers upon the soft template.Surfaces with nanostructures such as nanotubes,nanorings or nanomembranes were realized.

关 键 词：ELECTROPOLYMERIZATION Soft template Reverse micelles Porous nanostructures 

分 类 号：TB383[一般工业技术—材料科学与工程]