河南省18个城市大气污染物分布特征、区域来源和传输路径  

One-year Simulation of Air Pollution in Central China,Characteristics,Distribution,Inner Region Cross-transmission,and Pathway Research in 18 Cities

作　　者：刘光瑾 苏方成 徐起翔 张瑞芹[2,3] 王克[2,3] LIU Guang-jin;SU Fang-cheng;XU Qi-xiang;ZHANG Rui-qin;WANG Ke(College of Chemistry,Zhengzhou University,Zhengzhou 450001,China;Research Institute of Environmental Science,Zhengzhou University,Zhengzhou 450001,China;School of Ecology and Environment,Zhengzhou University,Zhengzhou 450001,China)

机构地区：[1]郑州大学化学学院,郑州450001 [2]郑州大学环境科学研究院,郑州450001 [3]郑州大学生态与环境学院,郑州450001

出　　处：《环境科学》2022年第8期3953-3965,共13页Environmental Science

基　　金：国家重点研发计划项目(2017YFC0212403);中央引导地方科技发展专项资金计划项目(HN 2016-149)。

摘　　要：河南省大气污染严重且与周边区域污染传输及交互影响明显,以2017年1、4、7和10月为研究对象,将河南省内18个地市的排放源分别标记,并应用于WRF-CMAQ溯源模型进行模拟.污染物分布结果表明,由于排放和气象的共同影响,河南省PM_(2.5)、NO_(2)和SO_(2)浓度表现为冬季最高,夏季最低.O_(3)-8h浓度的季节变化则为夏季最高,春季次之,冬季最低.不同季节间污染物浓度差距较大,河南省PM_(2.5)、NO_(2)和SO_(2)冬季浓度平均值分别是夏季的4.17、4.12和6.24倍,而O_(3)-8h在夏季的浓度是冬季的2.24倍.由于PM_(2.5)、NO_(2)和SO_(2)与一次排放关系密切且具有一定的同源性,这3种污染物的高值分布为北高南低,季节趋势较为一致.而O_(3)-8h季节分布差异较大,夏季气象条件有助于O_(3)的生成,O_(3)-8h高值主要分布于河南省东北区域;冬春秋季由于气象条件的抑制和NO_(x)的消耗O_(3)-8h高值主要分布在河南省的南部.传输结果表明,冬季省外传输和天然源对河南省PM_(2.5)、O_(3)-8h、NO_(2)和SO_(2)浓度的贡献率都是最大的,分别为36.20%~72.32%、77.96%~96.08%、49.45%~78.80%和59.05%~88.85%.在仅考虑本地排放和省内传输时,夏季河南省内各市的排放对本地4种污染物浓度的贡献率均为最高;春季省内传输对各市PM_(2.5)和O_(3)-8h浓度的贡献率较大,分别为25.63%~74.69%和30.21%~80.01%,冬季省内传输对各市NO_(2)和SO_(2)浓度的贡献率较大,分别为26.02%~76.96%和20.30%~82.34%.河南省内PM_(2.5)、NO_(2)和SO_(2)的传输路径相似,冬季多由北向南传输,春季多由西向东,西南向东北传输,夏季多由西南向东北传输,秋季多由北向南传输,但PM_(2.5)的传输更加复杂.而O_(3)-8h传输路径与其他3种较为不同,特别是在秋季O_(3)-8h由西南向东北的传输路径明显.Air pollution in Henan province is serious and is significantly impacted by pollution transmission and interactions with surrounding areas.The emission sources in 18 cities in Henan province were labeled and applied to the WRF-CMAQ traceability model for simulation in January,April,July,and October of 2017.The pollutant distribution results showed that due to the combined influence of emissions and meteorology,the concentrations of PM_(2.5),NO_(2),and SO_(2) in Henan province were the highest in winter and the lowest in summer.The seasonal variation in O_(3)-8 h concentration was the highest in summer,followed by spring,and the lowest in winter.There was a large difference in pollutant concentrations between different seasons.The average concentrations of PM_(2.5),NO_(2),and SO_(2) in winter in Henan province were 4.17,4.12,and 6.24 times those in summer,respectively,whereas the concentration of O_(3)-8 h in summer was 2.24 times that in winter.Since PM_(2.5),NO_(2),and SO_(2) are closely related to primary emissions and have a certain homology,the distributions of high values of these three pollutants were higher in the north and lower in the south,and the seasonal trends were more consistent.The seasonal distribution of O_(3)-8 h varied widely,with high O_(3)-8 h values mainly distributed in the northeastern region of Henan province in summer,when meteorological conditions contributed to O_(3) production;in winter,spring,and autumn,high O_(3)-8 h values were mainly distributed in the southern part of Henan province due to the suppression of meteorological conditions and NO_(x) consumption.The results of the study on the transport of pollutants showed that extra-provincial transport and natural sources contributed the most to the concentrations of PM_(2.5),O_(3)-8 h,NO_(2),and SO_(2) in winter,with 36.20%-72.32%,77.96%-96.08%,49.45%-78.80%,and 59.05%-88.85%,respectively.When considering only local emissions and intra-provincial transmission,the contributions of emissions to local concentrations of the four pollu

关 键 词：河南省 WRF-CMAQ模型 排放溯源 区域传输 传输路径 

分 类 号：X511[环境科学与工程—环境工程]