MIL-88活化玻碳电极的构建及对葛根素的检测  

Construction of electrodeposited mil-88 modified activated glassy carbon electrode and detection of puerarin

作　　者：郑子祺 邱佳淇 肖广钊 黄晓彤 李宏峰 翟海云 ZHENG Zi-qi;QIU Jia-qi;XIAO Guang-zhao;HUANG Xiao-tong;LI Hong-feng;ZHAI Hai-yun(College of Pharmacy,Guangdong Pharmaceutical University,Guangzhou 510006,China)

机构地区：[1]广东药科大学药学院,广东广州510006

出　　处：《化学研究与应用》2022年第8期1753-1760,共8页Chemical Research and Application

基　　金：广东省自然科学基金项目(2021A1515011410)资助;广东省大学生创新训练项目(S202110573007)资助。

摘　　要：采用i-t法将MIL-88沉积到活化玻碳电极(AGCE)上,得到MIL-88/AGCE修饰电极,将其用于葛根素的电化学检测。利用循环伏安法(CV)和线性扫描伏安法(LSV)研究葛根素在MIL-88/AGCE上的电化学行为。葛根素的线性范围为1.0~50.0μM,相关系数r为0.9941,检出限为0.53μM(S/N=3)。此修饰电极可应用于中药材葛根粉中葛根素的含量测定,回收率为95.60%~100.0%。MIL-88 was deposited on activated glassy carbon electrode(AGCE)by i-t method,and a new electrochemical sensor constructed by MIL-88/AGCE was obtained for the electrochemical detection of puerarin.Cyclic voltammetry(CV)and linear sweep voltammetry(LSV)were used to study the electrochemical behavior of puerarin on MIL-88/AGCE.The linear range of puerarin is 1.0~50.0μM,the correlation coefficient r is 0.9941,and the limit of detection is 0.53μM(S/N=3).The method has been successfully applied to determine puerarin in Radix Puerariae,and the recoveries are 95.60%~100.0%.

关 键 词：电沉积 葛根素 电化学传感器 金属有机骨架 

分 类 号：O657.1[理学—分析化学]