电炉法制磷过程热力学及动力学分析  

Thermodynamics and kinetics analysis of phosphorus production by electric-furnace method

作　　者：朱志伟 唐远 李智力[1] 何东升[1] 姚远 Zhiwei ZHU;Yuan TANG;Zhili LI;Dongsheng HE;Yuan YAO(School of Resource and Safety Engineering,Wuhan Institute of Technology,Wuhan,Hubei 430074,China;Changsha Institute of Mining Research Co.,Ltd.,Changsha,Hunan 410012,China;Chemical Engineering College,Zhengzhou University,Zhengzhou,Henan 450001,China)

机构地区：[1]武汉工程大学资源与安全工程学院,湖北武汉430074 [2]长沙矿山研究院有限责任公司,湖南长沙410012 [3]郑州大学化工学院,河南郑州450001

出　　处：《过程工程学报》2022年第7期927-934,共8页The Chinese Journal of Process Engineering

基　　金：国家重点基础研究计划项目(编号:2019YFC1905801);湖北省尾矿(渣)资源化利用工程技术研究中心项目(编号:2019ZYYD070);武汉工程大学科学基金研究项目(编号:K2021099)。

摘　　要：采用FactSage软件对电炉法制磷过程中的渣系相图进行计算,并对体系内相关组分的助熔效果进行了分析。考察了不同温度下PO的还原率差异,并对反应过程进行了热力学和动力学分析。结果表明,当酸度值M为0.75~0.85时,AlO含量对体系形成低共熔物及调节低共熔温度存在一定影响,且适当增大AlO含量对电炉法制磷过程更有利。单一添加MgO作助熔剂不能有效促进炉料熔融,且会使共熔温度升高,因此应考虑与其他助熔剂复配使用。磷矿熔融还原反应符合一级反应特征,体系的表观活化能为165.712 k J/mol。Yellow phosphorus is an importan industrial raw material for the development of phosphorus chemical industry in China. The yellow phosphorus production by electric-furnace method has always been the core of thermal process for phosphate rock treatment. The electric-furnace method should be able to make direct use of the low-grade phosphate rocks, especially those with high silicon content, but this would consume a lo of energy. The researchers note that attention should be given to the formation of eutectic and the adjustment of eutectic temperature. A large number of experimental studies are obtained to discuss the macroscopic effect of different strengthening means of phosphate rock reduction. However, the mechanism is mostly inferred. At present, the lack of objective presentation of the eutectic composition and transformation hinders the clear explanation of those mechanisms. Thus, it is necessary to study the phase diagram of slag and the melting aid effect in the phosphorus production process by means of chemical thermodynamics computation. It is of great realistic and scientific significance to reveal the interaction mechanism and improve an electric-furnace technology of phosphorus production. In this work, the phase diagram and melting mechanism in the phosphorus production process by electric-furnace method were studied with FactSage 8.0 computation. It showed that levels of AlOhad a certain effect on the formation of eutectic and the adjustment of eutectic temperature. With the proper increase of AlOcontent, the phosphorus production process was improved. In contrast, the single MgO as a flux was unable to effectively promote the charge melting and the eutectic temperatures were likely to rise. Beyond these points, the melting reduction reaction of the phosphate rock was demonstrated to be consistent with the first-order reaction characteristics.

关 键 词：电炉法 FactSage软件 助熔剂 热力学 动力学 

分 类 号：TQ126.31[化学工程—无机化工]