Review on Heteroatom Doping Carbonaceous Materials Toward Electrocatalytic Carbon Dioxide Reduction  

作　　者：Youan Ji Juan Du Aibing Chen 

机构地区：[1]College of Chemical and Pharmaceutical Engineering,Hebei University of Science and Technology,Shijiazhuang 050018,China

出　　处：《Transactions of Tianjin University》2022年第4期292-306,共15页天津大学学报（英文版）

基　　金：financially supported by the Natural Science Foundation of Hebei Province (B02020208088, H2020206514, and B2021208074);the S&T Program of Hebei Province (20544401D, 20314401D, 206Z4406G, 21314402D, 21344601D, 22344402D, and 22373709D);the Research Start-up Funding at Hebei University of Science and Technology (1181381)

摘　　要：Carbon dioxide(CO_(2))reduction into chemicals or fuels by electrocatalysis can eff ectively reduce greenhouse gas emissions and alleviate the energy crisis.Currently,CO_(2)electrocatalytic reduction(CO_(2)RR)has been considered as an ideal way to achieve“carbon neutrality.”In CO_(2)RR,the characteristics and properties of catalysts directly determine the reaction activity and selectivity of the catalytic process.Much attention has been paid to carbon-based catalysts because of their diversity,low cost,high availability,and high throughput.However,electrically neutral carbon atoms have no catalytic activity.Incorpo-rating heteroatoms has become an eff ective strategy to control the catalytic activity of carbon-based materials.The doped carbon-based catalysts reported at present show excellent catalytic performance and application potential in CO_(2)RR.Based on the type and quantity of heteroatoms doped into carbon-based catalysts,this review summarizes the performances and catalytic mechanisms of carbon-based materials doped with a single atom(including metal and without metal)and multi atoms(including metal and without metal)in CO_(2)RR and reveals prospects for developing CO_(2)electroreduction in the future.

关 键 词：Heteroatoms doping Carbonaceous materials CO_(2)reduction ELECTROCATALYTIC 

分 类 号：O643.36[理学—物理化学] X701[理学—化学]