金属卟啉在催化氧化反应中的研究进展  

Progress in the application of metalloporphyrins compounds in catalytic oxidation reactions

作　　者：刘晓辉[1] 周哲韩 周贤太[1] 纪红兵[2] Xiaohui Liu;Zhehan Zhou;Xiantai Zhou;Hongbing Ji(Fine Chemical Industry Research Institute,School of Chemical Engineering and Technology,Sun Yat-sen University,Zhuhai 519082,China;Fine Chemical Industry Research Institute,School of Chemistry,Sun Yat-sen University,Guangzhou 510275,China)

机构地区：[1]中山大学精细化工研究院,化学工程与技术学院,珠海519082 [2]中山大学精细化工研究院,化学学院,广州510275

出　　处：《中国科学：化学》2022年第8期1224-1238,共15页SCIENTIA SINICA Chimica

基　　金：国家重点研发计划项目(编号:2020YFA0210900);国家自然科学基金(编号:21938001,21878344)资助项目。

摘　　要：金属卟啉作为P-450酶的有效模拟物,因在仿生催化氧化体系中具有效率高、选择性好、条件温和等特点,备受人们关注.本文详细介绍了近年来金属卟啉配合物作为催化剂在氧化反应方面的应用,主要包括烷烃、烯烃、醇、酮等底物的氧化,并对可能的反应机理、活性物种进行了总结.最后,展望了金属卟啉在氧化反应中的挑战与前景.Metalloporphyrins,as model compounds of P-450 enzyme,have been widely used in biomimetic catalytic oxidation reactions.The biomimetic catalytic oxidation system developed by metalloporphyrins has been gathering much attention due to the characteristics of high efficiency,good selectivity and mild conditions.In this paper,the application of metalloporphyrins as catalysts for the catalytic oxidation were reviewed,mainly including the oxidation of alkanes,olefins,alcohols,ketones and other substrates.The possible reaction mechanism and active species were summarized.Last,the challenges and prospects of metalloporphyrins complexes in catalytic oxidation were discussed.

关 键 词：仿生催化 金属卟啉 氧化反应 反应机理 均相氧化 

分 类 号：TQ203.2[化学工程—有机化工]