卟啉酞菁:从分子材料到聚集态  

Porphyrin and phthalocyanine:from molecular materials to aggregates

作　　者：赖泓宇 王宁[1] 李玉良 Hongyu Lai;Ning Wang;Yuliang Li(Science Center for Material Creation and Energy Conversion,School of Chemistry and Chemical Engineering,Institute of Frontier and Interdisciplinary Science,Shandong University,Jinan 250100,China;Key Laboratory of Organic Solids,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China)

机构地区：[1]山东大学物质创制与能量转换科学研究中心,化学与化工学院,前沿交叉科学研究院,济南250100 [2]中国科学院化学研究所有机固体实验室,北京100190

出　　处：《中国科学：化学》2022年第8期1259-1277,共19页SCIENTIA SINICA Chimica

基　　金：国家自然科学基金(编号:21790050,21790051,21875274);国家重点研发项目(编号:2018YFA0703501);中国科学院重点项目(编号:QYZDY-SSW-SLH015);山东大学齐鲁青年学者基金资助项目。

摘　　要：卟啉酞菁类分子材料作为关键组分广泛应用于储能转换、光电子、催化、生物传感器等研究领域中.为了满足不同领域的实际需求,本课题组系统开展了分子结构设计、聚集态组装过程控制的相关研究,并对卟啉酞菁类材料的本征性质、聚集态形貌进行了系统的调控.本综述从卟啉酞菁类分子材料的分子结构修饰、聚集态调控和器件应用等方面出发,总结并讨论了相关领域的最新研究成果.此外,结合有机合成化学和自组装技术的设计策略,详细介绍了该类材料的设计原则、功能化结构修饰、自组装行为、器件应用和发展前景,为相关材料的设计与合成提供了重要的研究思路.Molecular materials based on porphyrin and phthalocyanine are widely used as key components in the fields of energy storage conversion,photoelectronics,catalysis,and biomedicine.In order to meet the actual needs of different types of applications,molecular structure design and aggregation process control are being systematically carried out.The intrinsic properties and aggregation morphology of porphyrin and phthalocyanine molecules are systematically regulated.This review summarizes and discusses the research achievements of molecular materials based on porphyrin and phthalocyanine in the aspect of molecular structure modification,aggregation regulation,and device applications.The functionalization and development prospect of porphyrin and phthalocyanine-based materials are introduced in detail by combining the design strategy of organic synthetic chemistry and self-assembly technology.It provides important research ideas for the design and synthesis of related materials.

关 键 词：卟啉 酞菁 分子材料 聚集态 

分 类 号：O641.3[理学—物理化学]