从废旧DVD光盘到电化学方法可控的SERS基底  

From old digital video disk to SERS strips with controllable electrochemical method

作　　者：郑强廷 薛路远[1] 李沁怡 吴一萍 文颖[1] 郭小玉[1] 杨海峰[1] ZHENG Qiangting;XUE Luyuan;LI Qinyi;WU Yiping;WEN Ying;GUO Xiaoyu;YANG Haifeng(College of Chemistry and Materials Science,Shanghai Normal University,Shanghai 200234,China)

机构地区：[1]上海师范大学化学与材料工程学院,上海200234

出　　处：《上海师范大学学报（自然科学版）》2022年第4期420-427,共8页Journal of Shanghai Normal University(Natural Sciences)

基　　金：The National Science Foundation of China(21475088)。

摘　　要：表面增强拉曼散射(SERS)光谱是一种高灵敏的检测技术,但制备高活性和低成本的SERS基底仍然是一大挑战.采用低成本的商业数字视频光盘(DVD)作为载体,用电化学技术原位合成金-银(Ag-Au)复合纳米结构作为SERS基底.通过电化学粗糙化技术,无需添加硝酸银(AgNO_(3))和四氯金酸(HAuCl4)前驱体溶液,就可以在DVD光盘上的沟槽状金银反射层表面上得到Ag-Au轨道团簇形态.经过一系列表征和优化,研究了Ag-Au复合纳米结构的SERS性能.结果表明:这种DVD衍生的SERS基底对不同的拉曼探针分子均表现出优异的增强性能、高均匀性(相对标准偏差(RSD)为7.88%)和出色的稳定性.这种简便高效的制备方法以及较高的SERS活性,使得DVD衍生的SERS基底成为开发便捷和一次性传感平台的较佳选择.For surface-enhanced Raman scattering(SERS)spectroscopy as a highly sensitive detection technique,the preparation of substrates with highly active and low cost remains a challenge.In this work,cheap commercial digital video disk(DVDs)were adopted as supports for in situ synthesis of Ag-Au composite nanostructure as SERS substrates by using electrochemical technique.Ag-Au orbital cluster morphology was obtained on the surface of gold and silver reflectors layer with a series of grooves in DVD through the method of electrochemical roughen technique,without addition of the precursor solution of AgNO_(3) and HAuCl4.After characterization and optimization,the SERS performances of the Ag-Au composite nanostructure were investigated.The results confirmed that this DVD-derived substrate exhibited excellent enhancement performance for different Raman probe molecules,high uniformity(relative standard deviation(RSD)is 7.88%),and better stability in the room temperature.Such a facile and effective preparation along with efficient SERS properties makes DVD-derived SERS substrates be very good candidates for the development of convenient and disposable sensing platforms.

关 键 词：表面增强拉曼散射(SERS) 电化学 数字视频光盘(DVD)基底 

分 类 号：O614.24[理学—无机化学]