Approaching Superior Potassium Storage of Carbonaceous Anode Through a Combined Strategy of Carbon Hybridization and Sulfur Doping  

作　　者：Qianqian Yao Yanmei Gan Zuju Ma Xiangying Qian Suzhi Cai Yi Zhao Lunhui Guan Wei Huang 

机构地区：[1]Fujian Cross Strait Institute of Flexible Electronics(Future Technologies),Fujian Normal University,Fuzhou 350117,China [2]CAS Key Laboratory of Design and Assembly of Functional Nanostructures,Fujian Key Laboratory of Nanomaterials,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350108,China [3]School of Environmental and Materials Engineering,Yantai University,Yantai 264005,China [4]Shaanxi InstituteofFlexibleElectronics(SIFE),NorthwesternPolytechnical University(NPU),Xi’an 710072,China [5]Key Laboratory of Flexible Electronics(KLOFE)&Institute of Advanced Materials(IAM),Nanjing Tech University(NanjingTech),Nanjing 211800,China

出　　处：《Energy & Environmental Materials》2022年第3期944-953,共10页能源与环境材料（英文）

基　　金：supported by National Natural Science Foundation of China(Grant 61935017,21701174,21771182);Projects of International Cooperation and Exchanges NSFC(Grant 51811530018);Synergetic Innovation Center for Organic Electronics and Information Displays;the Youth Innovation Promotion Associa tion CAS;the start-up funding from FJNU。

摘　　要：Carbonaceous materials are promising anode candidates for potassium-ion batteries(PIBs)given its high conductivity,stable property,and abundant resource,while its practical implementation is still hampered by its limited capacity and inferior rate behavior.Herein,we report a superior carbonaceous anode through a combined strategy of carbon hybridization and heteroatom doping.In this composite,hollow carbon spindles(HCS)were anchored on the surface of graphene(G)followed with sulfur doping treatment,aiming to integrate the high conductivity of graphene,the good structure stability of HCS,and the S doping-induced ample active sites.As a PIB anode,the S-G@HCS composite can display high capacity(301 mAh g^(-1)at 0.1 A g^(-1)after 500 cycles)and long-term cyclability up to 1800 cycles at 2 A g^(-1).Impressively,it can deliver an outstanding rate capacity of 215 mAh g^(-1)at 10 A g^(-1),which is superior to most carbon anodes as-reported so far for PIBs.Experimental and theoretical analysis manifests that the construction of graphene/amorphous carbon interface as well as S doping enables the regulation of electronic structure and ion adsorption/transportation properties of carbonaceous material,thus accounting for the high capacity and superior rate capability of S-G@HCS composite.

关 键 词：carbonaceous anode graphene hollow carbon spindles potassium-ion batteries sulfur doping 

分 类 号：TQ127.11[化学工程—无机化工] TM912[电气工程—电力电子与电力传动]