硼簇-咔唑功能材料的制备与性能研究综合实验设计  

Design of comprehensive experiment on preparation and properties of boron cluster-carbazole

作　　者：李军峰[1] 陈雨 马加勉 戴岚清 史姝楠 LI Junfeng;CHEN Yu;MA Jiamian;DAI Lanqing;SHI Shunan(State Key Laboratory of Organic Electronics and Information Displays,College of Chemistry and Life Science,Nanjing University of Posts&Telecommunications,Nanjing 210023,China)

机构地区：[1]南京邮电大学化学与生命科学院省部共建有机电子与信息显示国家重点实验室,江苏南京210023

出　　处：《实验技术与管理》2022年第9期207-210,245,共5页Experimental Technology and Management

基　　金：国家自然科学基金项目(21975130)。

摘　　要：硼簇光电材料的开发逐渐成为信息显示领域的研究热点,该实验将此方面的最新科研成果引入了大学化学综合实验。实验通过咔唑-碳硼烷结构的光电材料制备、结构表征与性能研究,能够使学生掌握基本的无水无氧操作,理解Sonogashira与杂化的狄尔斯-阿尔德(Diels-Alder)等偶联反应原理,熟悉核磁共振、紫外-可见吸收光谱、荧光光谱等现代表征技术,理解聚集诱导发光现象的本质,拓展理论知识视野,提升综合思维能力与实践操作能力,激发实验科学兴趣。The development of boron cluster-carbazole optoelectronic materials has gradually become a hot spot in the field of information display. This experiment introduces the latest scientific research achievements in this field into the comprehensive experimental course of chemistry. Through the research on the preparation, structural characterization and performance of the photoelectric materials with carbazole carborane structure, students can master the basic anhydrous and oxygen free operations, understand the coupling reaction principles of Sonogashira and hybrid Diels-Alder, be familiar with modern characterization technologies such as nuclear magnetic resonance(NMR) spectra, UV-Vis absorption, fluorescence spectrum, etc. They can understand the essence of aggregationinduced(AIE) luminescence phenomenon, expand the horizon of theoretical knowledge, improve the comprehensive thinking ability and practical operation ability, and stimulate the interest in experimental science.

关 键 词：综合化学实验 硼簇 咔唑 聚集诱导发光 狄尔斯-阿尔德 

分 类 号：O6-3[理学—化学] G642.0[文化科学—高等教育学]