超交联聚合物在样品前处理和色谱分离中的应用  

Application of Hypercrosslinked Polymers in Sample Pretreatment and Chromatographic Separation

作　　者：王东泽 王宇轩 贾琼[2] WANG Dong-Ze;WANG Yu-Xuan;JIA Qiong(College of Plant Protection,Jilin Agricultural University,Changchun 130118,China;College of Chemistry,Jilin University,Changchun 130012,China)

机构地区：[1]吉林农业大学植物保护学院,长春130118 [2]吉林大学化学学院,长春130012

出　　处：《分析化学》2022年第10期1435-1443,共9页Chinese Journal of Analytical Chemistry

基　　金：长春市科技计划项目(No.21ZGN35)资助。

摘　　要：超交联聚合物(HCPs)是一类由芳香族化合物通过傅-克烷基化反应构建的多孔有机聚合物,具有良好的化学稳定性、较高的比表面积、可调节的孔径、合成条件简单以及易于功能化等特点,在样品前处理和色谱分离中展现了极大的发展潜力。本文介绍了HCPs在固相萃取(SPE)、磁固相萃取(MSPE)、固相微萃取(SPME)、高效液相色谱(HPLC)和气相色谱(GC)等领域的应用和研究进展,并对HCPs在分离科学方面的应用前景进行了展望。Hypercrosslinked polymers(HCPs)are a kind of porous organic polymers built from aromatic compounds via Friedel-Crafts acylation.Due to their excellent chemical stability,extremely high specific surface area,adjustable pore size,simple synthesis condition and easy functionalization,HCPs have shown great potential in sample pretreatment and chromatographic separation.In this article,the application and progress of HCPs in solid phase extraction(SPE),magnetic solid phase extraction(MSPE),solid phase microextraction(SPME),high performance liquid chromatography(HPLC)and gas chromatography(GC)are systematically reviewed.In the end,the outlook about the application of HCPs in separation science is prospected.

关 键 词：超交联聚合物 样品前处理 色谱分离 评述 

分 类 号：TQ317[化学工程—高聚物工业] O652.6[理学—分析化学]