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作 者:Huimin Huang Zijun Wu Zhijian Zhou Qiulin Xu Jie Yan Qiaoguang Li
机构地区:[1]College of Chemistry and Chemical Engineering,Zhongkai University of Agriculture and Engineering,Guangzhou,510225,China [2]College of Light Industry and Food Science,Zhongkai University of Agriculture and Engineering,Guangzhou,510225,China
出 处:《Journal of Renewable Materials》2023年第1期257-272,共16页可再生材料杂志(英文)
基 金:supported by the Guangdong Provincial Science and Technology Project(No.2015B020215012);State Key Laboratory of Woody Oil Resource Utilization,Co-Built by Provincial and Ministry of China(No.GZKF202108);National Natural Science Foundation of China(32101475).
摘 要:The low utilization rate of pesticides makes the migration of pesticides in water and soil,which brings great harm to the ecosystem.The development of pesticide carriers with good drug loading capacity and release control abil-ity is an effective method to realize effective utilization of pesticides and reduce pesticide losses.In this work,fosthiazate-stearic acid/expanded perlite sustained-release particles were successfully prepared by vacuum impregnation using expanded perlite(EP)as carrier,fosthiazate(FOS)as model pesticide and stearic acid(SA)as hydrophobic matrix.The structure and morphology of the samples were studied by BET,FT-IR,TGA,XRD,DSC and SEM.The effects of different mass ratios of FOS to SA on loading capacity and release rate at 24 h were investigated.The sustained release behavior of FOS-SA/EP at different temperatures and pH values was investigated by static dialysis bag method.The results showed that FOS and SA were adsorbed in EP pores by physical interaction.With the mass ratios of FOS to SA decreasing from 7:3 to 3:7,the 24 h release rate of FOS-SA/EP decreased from 18.77%to 8.05%,and the drug loading decreased from 461.32 to 130.99 mg/g.FOS-SA/EP showed obvious temperature response at 25℃,30℃ and 35℃,the cumulative release rate(CRR)of 200 h were 33.38%,41.50%and 51.17%,respectively.When pH=5,the CRR of FOS was higher than that of pH=7,and the CRR of FOS for 200 h were 49.01%and 30.12%,respectively.At different temperatures and pH=5,the release mechanism of FOS-SA/EP belongs to the Fickian diffusion mechanism;When pH=7,the diffusion mechanism is dominant,and the dissolution mechanism is complementary.
关 键 词:Expanded perlite FOSTHIAZATE stearic acid sustained release release kinetics
分 类 号:TU551.34[建筑科学—建筑技术科学]
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