Structure and Morphology of Poly(ε-caprolactone)Heterogeneous Shish-Kebab Structure Induced by Poly(lactic acid)Nanofibers  

作　　者：Zhong-Hua Chang Dong-Fang Wang Yi-Yang Xu Meng-Yuan Zhang Qian Li 

机构地区：[1]School of Mechanics and Safety Engineering,Zhengzhou University,Zhengzhou 450001,China [2]National Center for International Research of Micro-Nano Molding Technology,Zhengzhou University,Zhengzhou 450001,China [3]School of Materials Science and Engineering,Zhengzhou University,Zhengzhou 450001,China

出　　处：《Chinese Journal of Polymer Science》2022年第10期1223-1232,I0009,共11页高分子科学（英文版）

基　　金：the financial support from the National Center for International Joint Research of Micro-Nano Molding Technology in China;the International Science&Technology Cooperation Program of China(No.2015DFA30550)。

摘　　要：In recent years,the hybrid shish-kebab structure with excellent physical properties and functionalities has attracted much attention because it provides a way of blending nanofibers with different properties into polymer matrix in a regular arrangement.It is often not easy to induce the formation of the hierarchically ordered structure for the semi-crystalline polymer in heterogeneous shish-kebab structure.A poly(lactic acid)(PLA)/poly(ε-caprolactone)(PCL)heterogeneous shish-kebab structure,i.e.,the PCL crystals periodically crystallized onto PLA nanofibers,was successfully created and the interfacial crystal morphology of the PLA/PCL heterogeneous shish-kebab structure was observed using scanning electron microscopy and atomic force microscopy.NaOH aqueous solution was applied to modify the surface of the PLA nanofibers to produce adsorption sites and carboxyl groups.The total reflectance Fourier transform infrared spectroscopy(ATR-FTIR)and X-ray diffraction(XRD)results demonstrated that the formation of the heterogeneous shish-kebab structure was mainly due to the hydrogen bonding interaction between the kebab and shish interface,and the growth process of the kebab crystals also promoted the crystallization of the shish fibers.This heterogeneous nanostructure of biodegradable polymers will have great applications in tissue engineering and regenerative medicine.

关 键 词：Shish-kebab structure PCL PLA CRYSTALLIZATION Surface modification 

分 类 号：TQ317[化学工程—高聚物工业]