现场生成的金属纳米团簇催化的研究进展  

Recent Process in the in situ Generated Metal Nanocluster Catalysis

作　　者：张金羽 刘天芬 王乐 王晓明[2] Zhang Jinyu;Liu Tianfen;Wang Le;Wang Xiaoming(College of Chemistry and Chemical Engineering,Shanghai University of Engineering Science,Shanghai 201620;Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032)

机构地区：[1]上海工程技术大学化学化工学院,上海201620 [2]中国科学院上海有机化学研究所,上海200032

出　　处：《有机化学》2022年第8期2331-2341,共11页Chinese Journal of Organic Chemistry

摘　　要：在一个金属催化体系中,不论催化剂前体是金属盐、金属络合物或纳米粒子,在反应过程中都可能现场发生转变生成单核络合物、多核团簇和纳米粒子等.综述了在一些代表性的金属催化的合成方法学中现场生成的纳米团簇粒子为催化活性物种的例子,并讨论纳米团簇粒子的形成、表征以及其催化作用.In transition metal catalyzed reactions using simple metal salts,metal complexes,or nanoparticles as catalyst precursors,the metal sources may transfer to other species in situ,such as mono metal species,metal clusters and nanoparticles.Herein,the representative examples of the in situ generated metal nanoclusters as the catalytically active species in synthetic methodologies are reviewed,including their in situ formation,characterization and effect in catalysis.

关 键 词：现场生成 金属纳米团簇 催化方法学 过渡金属催化 

分 类 号：TB383.1[一般工业技术—材料科学与工程] O643.36[理学—物理化学]