三取代烯烃型聚集诱导发光分子的设计、合成与应用  

Design, Synthesis and Application of Trisubstituted Olefinic Aggregation-Induced Emission Molecules

作　　者：陈兆华 曹西颖 陈思鸿 宇世伟 林燕兰 林舒婷 汪朝阳[1] Chen Zhaohua;Cao Xiying;Chen Sihong;Yu Shiwei;Lin Yanlan;Lin Shuting;Wang Zhaoyang(School of Chemistry,South China Normal University,Key Laboratory of Theoretical Chemistry of Environment,Ministry of Education,Guangzhou Key Laboratory of Analytical Chemistry for Biomedicine,GDMPA Key Laboratory for Process Control and Quality Evaluation of Chiral Pharmaceuticals,Guangzhou 510006)

机构地区：[1]华南师范大学化学学院,教育部环境理论化学重点实验室,广州市生物医学分析化学重点实验室,广东省药品监督管理局手性药物过程控制与质量评价重点实验室,广州510006

出　　处：《有机化学》2022年第8期2355-2363,共9页Chinese Journal of Organic Chemistry

基　　金：广东省基础与应用基础研究基金(No.2021A1515012342);广东省科技计划(No.2017A010103016)资助项目。

摘　　要：聚集诱导发光(AIE)现象的发现开创了有机发光材料研究的新里程与新局面.AIE分子的研究广受关注,其中三取代烯烃型AIE分子作为近年来新出现的结构类型,它们的设计、合成与应用的进展也颇为显著.鉴于此,根据近年合成的三取代烯烃型AIE分子所连接的取代基的结构特点,将其细分为三芳(杂环)基取代的烯烃型AIE分子、双键相连氰基的三取代烯烃型AIE分子和双键相连杂原子的三取代烯烃型AIE分子三大类,重点综述了其分子作用机制,以及在有机发光材料、荧光探针等领域的应用,并对三取代型AIE分子的未来设计进行了展望.The discovery of aggregation-induced emission(AIE) has created a new milestone and new situation in the research of organic luminescence materials. The research on AIE molecules has attracted enormous attention. Among them, trisubstituted olefinic AIE molecules, as new structural types in recent years, have made remarkable progress in their design,synthesis and application. In view of this, according to the structural characteristics of the substituents attached to the carbon-carbon double bond, these trisubstituted olefinic AIE molecules synthesized in recent years are divided into three categories: olefinic AIE molecules substituted(a) by multiple aryl rings,(b) by cyano group(s) and(c) by heteroatoms. As this classification, their molecular mechanisms and applications in the field of organic luminescence materials and fluorescent probes are reviewed, and the future design of the trisubstituted AIE molecules is also prospected.

关 键 词：聚集诱导发光(AIE) 三取代烯烃 设计与合成 分子作用机制 有机发光材料 荧光探针 

分 类 号：O621.3[理学—有机化学]