可见光诱导甲酸盐参与的烯烃氢羧化反应  

Hydrocarboxylation of Alkenes with Formate Salts via Photocatalysis

作　　者：黄燕[1] 张谦[1] 詹乐武 侯静 李斌栋[1] Huang Yan;Zhang Qian;Zhan Lewu;Hou Jing;Li Bindong(College of Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094)

机构地区：[1]南京理工大学化学与化工学院,南京210094

出　　处：《有机化学》2022年第8期2568-2573,共6页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.21901118);江苏省自然科学基金(No.BK20190430);重点高校基础科研业务费专项资金(No.30921011206)资助项目.

摘　　要：发展了一种温和条件下以甲酸盐作为还原剂和羰基来源的β-选择性烯烃氢羧化反应.利用该方法,一系列的烯烃能够被有效地转化为高价值的羧酸产品.该方法具备催化剂用量小、官能团耐受性好、易于放大等特点.A transition-metal-freeβ-selective hydrocarboxylation of alkenes under mild conditions has been developed using a formate salt as the reductant,carbonyl source.A broad range of alkenes were compatible with this method and can be efficiently converted into value-added carboxylic acid products.This method also features low catalyst loading,good functional group tolerance,and easy scalability.

关 键 词：烯烃 氢羧化 光催化 二氧化碳自由基负离子 甲酸盐 

分 类 号：O621.25[理学—有机化学]